University of Huddersfield Logo

Portrait of Dr Lindsay Harding Dr Lindsay Harding

l.p.harding@hud.ac.uk | 01484 472434



Biography

My research interests are in the area of analytical chemistry and I also run the School's NMR and mass spectrometry facilities. I have over 50 papers in various areas of analytical chemistry and collaborate with partners both across the UK and internationally.

I teach mass spectrometry, NMR and chromatography to second and final year undergraduates and am also the Second Year Tutor for Chemistry students.

Research & Scholarship

My main research interests are in the synthesis and characterisation of novel coordination complexes.

Current projects include:

  • Synthesis of novel coordination complexes incorporating molecules of biological interest
  • Use of chemoenzymatic synthesis to prepare building blocks for coordination complexes
  • Characterisation of metallosupramolecular species in the solution state

Publications and Other Research Outputs

$VAR1 = { '3463' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Tidmarsh', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Ian S.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Al-Rasbi', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Nawal K.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '3463', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '53', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Mixed-Ligand Molecular Paneling: Dodecanuclear Cuboctahedral Coordination Cages Based on a Combination of Edge-Bridging and Face-Capping Ligands', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/63', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '14', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ja803847w', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '20', 'publisher' => 'American Chemical Society', 'pagerange' => '11641-11649', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '53', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '53', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 8, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3463', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080800', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '16', 'number' => '35', 'rev_number' => '10', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '14', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'Reaction of a tris-bidentate ligand L1 (which can cap one triangular face of a metal polyhedron), a bis-bidentate ligand L2 (which can span one edge of a metal polyhedron), and a range of M2+ ions (M = Co, Cu, Cd), which all have a preference for six coordination geometry, results in assembly of the mixed-ligand polyhedral cages [M12(?3-L1)4(?-L2)12]24+. When the components are combined in the correct proportions [M2+:L1:L2 = 3:1:3] in MeNO2, this is the sole product. The array of 12 M2+ cations has a cuboctahedral geometry, containing six square and eight triangular faces around a substantial central cavity; four of the eight M3 triangular faces (every alternate one) are capped by a ligand L1, with the remaining four M3 faces having a bridging ligand L2 along each edge in a cyclic helical array. Thus, four homochiral triangular {M3(L2)3}6+ helical units are connected by four additional L1 ligands to give the mixed-ligand cuboctahedral array, a topology which could not be formed in any homoleptic complex of this type but requires the cooperation of two different types of ligand. The complex [Cd3(L2)3(ClO4)4(MeCN)2(H2O)2](ClO4)2, a trinuclear triple helicate in which two sites at each Cd(II) are occupied by monodentate ligands (solvent or counterions), was also characterized and constitutes an incomplete fragment of the dodecanuclear cage comprising one triangular {M3(L2)3}6+ face which has not yet reacted with the ligands L1. 1H NMR and electrospray mass spectrometric studies show that the dodecanuclear cages remain intact in solution; the NMR studies show that the Cd12 cage has four-fold (D2) symmetry, such that there are three independent Cd(II) environments, as confirmed by a 113Cd NMR spectrum. These mixed-ligand cuboctahedral complexes reveal the potential of using combinations of face-capping and edge-bridging ligands to extend the range of accessible topologies of polyhedral coordination cages. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '14', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1021/ja803847w', 'volume' => '130', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '571' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Felton', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Cara E.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Coldwell', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Jonathan B.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Moon', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Ryan', 'creators_id' => 'r.moon@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '571', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '35', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Barium induced modulation of NIR emission in a neodymium cryptate complex', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/71', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '43', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b612662f', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '5048-5050', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '22', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1364-548X', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '35', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '571', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20060000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => undef, 'rev_number' => '19', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '54', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'The complex [NdL]III is based upon a crown ether-appended ditopic cryptate ligand and demonstrates a near-infrared fluorescence response to Ba', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '54', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/b612662f', 'volume' => '2006', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1 T. Gunnlaugsson and J. P. Leonard, Chem. Commun., 2005, 3114; S. Pandya, J. Yu and D. Parker, Dalton Trans., 2006, 2757; J.-C. G. Bu¨nzli and C. Piguet, Chem. Soc. Rev., 2005, 34, 1048. 2 P. Caravan, Chem. Soc. Rev., 2006, 35, 512; S. Faulkner, S. J. A. Pope and B. P. Burton-Pye, Appl. Spectrosc. Rev., 2005, 40, 1. 3 P. R. Slevin, Annu. Rev. Biophys. Biomol. Struct., 2002, 31, 275; D. Parker, in Supramolecular Science: Where it is and Where it is Going, ed. R. Ungaro and E. Delcanale, Kluwer, Dordrecht, 1999, vol. C527, pp. 53–67. 4 R. S. Dickins, J. A. K. Howard, C. L. Maupin, J. M. Moloney, D. Parker, J. P. Riehl,G. Siligardi and J. A. G.Williams, Chem.–Eur. J., 1999, 5, 1095;D. Parker, Coord. Chem. Rev., 2000, 205, 109; R. A. Poole, G. Bobba,M. J. Cann, J.-C. Frias,D. Parker and R. D. Peacock, Org. Biomol. Chem., 2005, 3, 1013; T. Terai, K. Kikuchi, S.-Y. Iwasawa, T. Kawabe, Y. Hirata, Y. Urano and T. Nagano, J. Am. Chem. Soc., 2006, 128, 6938; M. de Sousa, M. Kluciar, S. Abad, M. A. Miranda, B. de Castro and U. Pischel, Photochem. Photobiol. Sci., 2004, 3, 639; A. P. de Silva, H. Q. N. Gunaratne and T. E. Rice, Angew. Chem., Int. Ed. Engl., 1996, 35, 2116; W. D. Horrocks, Jr, J. P. Bolender, W. D. Smith and R. M. Supkowski, J. Am. Chem. Soc., 1997, 119, 5972. 5 S. J. A. Pope and R. H. Laye, Dalton Trans., 2006, 3108. 6 M. H. V. Werts, R. H.Woudenberg, P. G. Emmerink, R. van Gassel, J. W. Hofstraat and J. W. Verhoeven, Angew. Chem., Int. Ed., 2000, 39, 4542. 7 For key examples see: S. I. Klink, H. Keizer and F. C. J.M. van Veggel, Angew. Chem., Int. Ed., 2000, 39, 4319; A. Beeby, R. S. Dickins, S. Fitzgerald, L. J. Govenlock, C. L. Maupin, D. Parker, J. P. Riehl, G. Siligardi and J. A. G. Williams, Chem. Commun., 2000, 1183; S. Faulkner and S. J. A. Pope, J. Am. Chem. Soc., 2003, 125, 10526; M.H.V.Werts, J.W.Hofstraat, F. A. G. Geurts and J.W.Verhoeven, Chem. Phys. Lett., 1997, 276, 196;D. Imbert,M. Cantuel, J.-C. Bu¨nzli, C. Bernardinelli and C. Piguet, J. Am. Chem. Soc., 2003, 125, 15698; N. M. Shevaleev, L. P. Moorcraft, S. J. A. Pope, Z. R. Bell, S. Faulkner and M. D. Ward, Chem. Commun., 2003, 1134; P. B. Glover, P. R. Ashton, L. J. Childs, A. Rodger, M. Kercher, R. M. Williams, L. De Cola and Z. Pikramenou, J. Am. Chem. Soc., 2003, 125, 9918; M.R. Sambrook, D. Curiel, E. J.Hayes, P.D. Beer, S. J. A. Pope and S. Faulkner, New J. Chem., 2006, 30, 1133. 8 M. Ramirez, M. Solache-Rios and A. Campero, Inorg. Chem., 1991, 30, 321. 9 N. Sabbatini, M. Guardigli and J.-M. Lehn, Coord. Chem. Rev., 1993, 123, 201. 10 A. Beeby and S. Faulkner, Chem. Phys. Lett., 1997, 266, 116. 11 A. Beeby, I. M. Clarkson, R. S. Dickins, S. Faulkner, D. Parker, L. Royle, A. S. de Sousa, J. A. G. Williams and M. Woods, J. Chem. Soc., Perkin Trans. 2, 1999, 493. 12 J.-C. Rodriguez-Ubis, B. Alpha, D. Plancharel and J.-M. Lehn, Helv. Chim. Acta, 1987, 91, 6136. 13 S. Faulkner, A. Beeby,M.-C. Carrie, A. Dadabhoy, A. M. Kenwright and P. G. Sammes, Inorg. Chem. Commun., 2001, 4, 187. 14 S. Yanagida, Y. Hasegawa, K. Murakoshi, Y. Wada and N. Nakashima, Coord. Chem. Rev., 1998, 171, 461. 15 C. J. Baylies, J. C. Jeffery, T. A. Miller, T. Riis-Johannessen and C. R. Rice, Chem. Commun., 2005, 4158; G. Bokolinis, T. Riis- Johannessen, L. P. Harding, J. C. Jeffery, N. McLay and C. R. Rice, Chem. Commun., 2006, 1980.', 'date_year' => '2006', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '519' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hinchliffe', 'eprintid' => '519', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Paul S.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '519', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Page', 'eprintid' => '519', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Michael I.', 'creators_id' => 'm.i.page@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '519', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Wood', 'eprintid' => '519', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'J. Matthew', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '53', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Novel mechanism of inhibiting b-lactamases by sulfonylation using b-sultams ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/19', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '19', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 15, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/j.bmcl.2003.08.082', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'Elsevier', 'pagerange' => '4489-4492', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Bioorganic & Medicinal Chemistry Letters', 'lastmod_second' => '46', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0960-894X', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '53', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 12, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '519', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20031215', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => '24', 'rev_number' => '20', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '28', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '8', 'datestamp_day' => '8', 'abstract' => '?-Sultams are the sulfonyl analogues of ?-lactams and N-acyl ?-sultams are novel inactivators of the class C ?-lactamase of Enterobacter cloacae P99. The rates of inactivation show a similar pH-rate dependence as that exhibited by the ?-lactam antibiotics and with ESIMS data it is suggested that ?-sultams sulfonylate the active site serine residue to form a sulfonate ester. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '28', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1016/j.bmcl.2003.08.082', 'volume' => '13', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1. Waley, S. G. In The Chemistry of -Lactams; Page, M. I., Ed.; Blackie: Glasgow, 1992; p 198. Fre` re, J.-M. Mol. Microbiol. 1995, 16, 385. 2. Payne, D. J. J. Med. Microbiol. 1993, 39, 93. Nordmann, P.; Mariotte, P. S.; Naas, T.; Labia, R.; Nicolas, M. H. Antimicrob. Agents Chemother. 1993, 37, 939. Naas, T.; Vandel, L.; Sougakoff, W.; Livermore, D. M.; Nordmann, P. Antimicrob. Agents Chemother. 1994, 38, 1262. 3. Bush, K.; Jacoby, G. A.; Modeiros, A. A. Antimicrob. Agents Chemother. 1995, 39, 1211. Rasmussen, B. A.; Bush, K. Antimicrob. Agents Chemother. 1997, 41, 223. 4. Page, M. I.; Laws, A. P. Chem. Commun. 1998, 1609. 5. Galleni, M.; Lamotte-Brassuer, J.; Rossolini, G. M.; Spencer, J.; Dideberg, O.; Fre` re, J. M. Antimicrob. Agents Chemother. 2001, 45, 660.6. Kelly, J. A.; Dideberg, O.; Charlier, P.; Wery, J.; Libert, M.; Moews, P.; Knox, J.; Duez; Fraipont; Joris, B.; Dusart, J.; Fre` re, J. M.; Ghuysen, J. M. Science 1986, 231, 1429. Samraoui, B.; Sutton, B.; Todd, R.; Artmiuk, P.; Waley, S. G.; Phillips, D. Nature 1986, 320, 378. Knox, J. R.; Moews, P. C. J. Mol. Biol. 1991, 220, 435. Moews, P. C.; Knox, J. R.; Dideberg, O.; Charlier, P.; Fre` re, J. M. Proteins: Struct., Funct., Genet. 1990, 7, 156. Herzberg, O.; Moult, J.-M. Science 1987, 236, 694. Herzberg, O. J. Mol. Biol. 1991, 217, 701. Dideberg, O.; Charlier, O.; We´ ry, J. P.; Dehottay, P.; Dusart, J.; Erpicum, T.; Fre` re, J. M.; Ghuysen, J.-M. Biochem. J. 1987, 245, 911. Lamotte-Brasseur, J.; Dive, G.; Dideberg, O.; Charlier, P.; Fre` re, J. M.; Ghuysen, J. M. Biochem. J. 1991, 279, 213. Jelsch, C.; Mourey, L.; Masson, J.-M.; Samama, J.- P. Proteins: Struct. Funct. Genet. 1993, 16, 364. 7. Oefner, C.; Darcy, A.; Daly, J. J.; Gubernator, K.; Charnas, R. L.; Heinze, I.; Hubschwerlen, C.; Winkler, F. K. Nature 1990, 343, 284. Lobkovsky, E.; Moews, P. C.; Hansong, L.; Haiching, Z.; Fre` re, J. M.; Knox, J. R. Proc. Natl. Acad. Sci. U.S.A. 1993, 90, 11257. Lobkovsky, E.; Billings, E. M.; Moews, P. C.; Rahill, J.; Pratt, R. F.; Knox, J. R. Biochemistry 1994, 33, 6762. Usher, K. C.; Blaszczak, L. C.; Weston, G. S.; Shoichet, B. K.; Remington, S. J. Biochemistry 1998, 37, 16082. 8. Damblon, C.; Zao, G. H.; Jamin, M.; Ledent, P.; Dubus, A.; Vanhove, M.; Raquet, X.; Christiaens, L.; Fre` re, J. M. Biochem. J. 1995, 309, 431. Xu, Y.; Soto, G.; Hirsch, K. R.; Pratt, R. F. Biochemistry 1996, 35, 3595. Murphy, B. P.; Pratt, R. F. Biochemistry 1991, 30, 3640. 9. Page, M. I.; Vilanova, B.; Layland, N. J. J. Am. Chem. Soc. 1995, 117, 12092. 10. Page, M. I. Enzyme Inhibition. In Comprehensive Medicinal Chemistry; Sammes, P. G., Ed.; Pergamon: Oxford, 1990; Vol. 2, p 61–87. 11. Wood, J. M.; Page, M. I. Trends Heterocycl. Chem. 2002, 8, 19. 12. Baxter, N. J.; Laws, A. P.; Rigoreau, L. J. M.; Page, M. I. J. Am. Chem. Soc. 2000, 112, 3375. Baxter, N. J.; Laws, A. P.; Rigoreau, L. J. M.; Page, M. I. J. Chem. Soc., Perkin Trans. 2 1996, 2245. 13. Beardsell, M.; Hinchliffe, P. S.; Wood, J. M.; Wilmouth, R. C.; Schofield, C. J.; Page, M. I. Chem. Commun. 2001, 1503. 14. Macdonald, S. J. F.; Dowle, M. D.; Harrison, L. A.; Spooner, J. E.; Shah, P.; Johnson, M. R.; Inglis, G. G. A.; Clarke, G. D. E.; Belton, D. J.; Smith, R. A.; Molloy, C. R.; Dixon, M.; Murkitt, G.; Godward, R. E.; Skarzynski, T.; Singh, O. M. P.; Kumar, K. A.; Hodgson; McDonald, E. G.; Hardy, W.; Finch, H.; Fleetwood, G.; Humphreys, D. C. Bioorg. Med. Chem. Lett. 2001, 11, 243. 15. Page, M. I.; Laws, A. P.; Slater, M. J.; Stone, J. R. Pure Appl. Chem. 1995, 67, 711. Laws, A. P.; Page, M. I.; Slater, M. J. Bioorg. Med. Chem. Lett. 1993, 3, 2317.', 'date_year' => '2003', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1204' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '1204', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => undef, 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '25', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Homo- and heteropolynuclear helicates with a ‘2 + 3 + 2’-dentate compartmental ligand', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/12/04', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '20', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b502423d', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '904-911', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'New Journal of Chemistry', 'lastmod_second' => '25', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1144-0546', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '25', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1204', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '8', 'number' => '7', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '20', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '24', 'datestamp_day' => '24', 'abstract' => 'An octadentate ligand L has been prepared which contains a sequence of bidentate (pyrazolyl-pyridine), terdentate [bis(pyrazolyl)pyridine] and bidentate (pyrazolyl-pyridine) binding sites separated by p-xylyl spacers. This forms a range of double helical complexes in which the two ligands define 4-, 6-, and 4-coordinate binding sites, and there is substantial -stacking between overlapping parallel areas of the ligands. In [Cu3L2][PF6]4 the sequence of oxidation states for the copper ions is +1, +2, +1 with the Cu(I) ions being four-coordinate at the terminal sites and Cu(II) being in the central six-coordinate site. In [Cu3(OAc)2L2][PF6]4 all copper centres are in oxidation state +2, with the terminal ions having an additional monodentate acetate ligand giving them a five-coordinate geometry. The 4 + 6 + 4 arrangement of coordination numbers means that reaction of L with a mixture of Fe(II) and Ag(I) results in high yield formation of [Ag2FeL2][BF4]4 in which Ag(I) ions occupy the terminal 4-coordinate sites and Fe(II) occupies the central pseudo-octahedral site. Reaction of L with Ag(I) produced a mixture of [Ag3L2][BF4]3(major product) and [Ag4L2][BF4]4(minor product). In [Ag3L2][BF4]3 the central Ag(I) ion is, unusually, in a pseudo-octahedral coordination environment from the two meridional, terdentate bis(pyrazolyl)pyridine donors. In [Ag4L2][BF4]4 in contrast the central 6-coordinate cavity is occupied by two Ag(I) ions separated by 2.85 . The terdentate chelating bis(pyrazolyl)pyridine units at the centre of the helicate are now substantially twisted such that each donates a bidentate pyrazolyl-pyridine to one Ag(I) centre and a monodentate pyrazole unit to the other. In solution, 1H NMR and mass spectroscopic evidence indicates that the fourth Ag(I) ion is lost and [Ag3L2][BF4]3 forms, unless a large excess of Ag(I) is present in which case traces of [Ag4L2][BF4]4 can be detected by mass spectrometry.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '20', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b502423d', 'volume' => '29', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2005', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3465' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rizkallah', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Pierre', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Carruthers', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Christopher', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Westcott', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Aleema', 'creators_id' => undef }, '7' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '7', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Sumby', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Christopher J.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Prior', 'eprintid' => '3465', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Timothy J.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '47', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'The Dimeric “Hand-Shake” Motif in Complexes and Metallo-Supramolecular Assemblies of Cyclotriveratrylene-Based Ligands', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/65', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '39', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 17, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/chem.200801264', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Wiley - VCH Verlag GmbH & Co. KGaA', 'pagerange' => '10286-10296', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemistry - A European Journal', 'lastmod_second' => '26', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '09476539', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '47', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 11, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3465', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20081117', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '33', 'rev_number' => '12', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '28', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which a ligand arm of one host is the intra-cavity guest of another and vice versa. This hand-shake motif is found in the trinuclear transition metal complex [Cu3Cl6(1)]CH3CN1.5 H2O in which 1 is tris(4-[2,2,6,2-terpyridyl]benzyl)cyclotriguaiacylene; in the self-included M4L4 tetrahedral metallo-supramolecular assembly [Ag4(2)4] (BF4)4 in which 2 is tris-(2-quinolylmethyl)cyclotriguaiacylene; in the 1D coordination chains [Ag(4)]ReO4 CH3CN and [Ag(5)]SbF63 DMFH2O in which 4 is tris(1H-imidazol-1-yl)cyclotriguaiacylene and 5 is tris{4-(2-pyridyl)benzyl}cyclotriguaiacylene; and in the acetone clathrate of tris{4-(2-pyridyl)benzyl-amino}cyclotriguaiacylene. Clathrates of ligands 2 and 5 do not show the same dimeric motif, although 2 has an extended homomeric inclusion motif that gives a hexagonal network', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '28', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/chem.200801264', 'volume' => '14', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '967' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '967', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '967', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '967', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'T', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Moon', 'eprintid' => '967', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Ryan', 'creators_id' => 'r.moon@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '967', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '14', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Allosteric deprogramming of a trinuclear heterometallic helicate', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/67', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '37', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b700539c', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '1577-1587', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '23', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '14', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '967', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '16', 'rev_number' => '13', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '48', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '3', 'datestamp_day' => '3', 'abstract' => 'Two multidentate ditopic ligands L1 and L2 which contain both N-donor and crown ether units have been synthesised. The potentially octadentate ligand L1 forms a trinuclear heterometallic double helicate with Cu(I) and Zn(II) ([Zn2Cu( L1)2]5+), whereas L2 forms a tetranuclear heterometallic double helicate with the same metal ions ([Zn2Cu2( L2)2]6+). Both species have been characterised by 1H NMR, ESI-MS and single crystal X-ray crystallography. Reaction of [Zn2Cu2( L2)2]6+ with Ba2+ results in the coordination of the crown ether units giving the simple barium coordinated species [Zn2Cu2( L2)2Ba2]10+. However, reaction of [Zn2Cu( L1)2]5+ with Ba2+ deprograms the ligand and results in the formation of a mixture of species.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '48', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b700539c', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '942' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Sykes', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Daniel', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Faulkner', 'eprintid' => '942', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Stephen', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '6', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '59', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N?,O-donor units: structures and luminescence properties', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/42', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '57', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b618258e', 'succeeds' => undef, 'datestamp_month' => '6', 'commentary' => undef, 'lastmod_day' => '30', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '1006-1022', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '59', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '59', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '942', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '6', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '8', 'number' => '10', 'rev_number' => '12', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '57', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '30', 'datestamp_day' => '30', 'abstract' => 'A set of three potentially bridging ligands containing two tridentate chelating N,N,O-donor (pyrazole–pyridine–amide) donors separated by an o, m, or p-phenylene spacer has been prepared and their coordination chemistry with lanthanide(III) ions investigated. Ligand L1 (p-phenylene spacer) forms complexes with a 2 : 3 M : L ratio according to the proportions used in the reaction mixture; the Ln2(L1)3 complexes contain two 9-coordinate Ln(III) centres with all three bridging ligands spanning both metal ions, and have a cylindrical (non-helical) mesocate architecture. The 1 : 1 complexes display a range of structural types depending on the conditions used, including a cyclic Ln4(L1)4 tetranuclear helicate, a Ln2(L1)2 dinuclear mesocate, and an infinite one-dimensional coordination polymer in which metal ions and bridging ligands alternate along the sequence. ESMS studies indicate that the 1 : 1 complexes form a mixture of oligonuclear species {Ln(L1)}n in solution (n up to 5) which are likely to be cyclic helicates. In contrast, ligands L2 and L3 (with o- and m-phenylene spacers, respectively) generally form dinuclear Ln2L2 Ln(III) complexes in which the two ligands may be arranged in a helical or non-helical architecture about the two metal ions. These complexes also contain an additional exogenous bidentate bridging ligand, either acetate or formate, which has arisen from hydrolysis of solvent molecules promoted by the Lewis-acidity of the Ln(III) ions. Luminescence studies on some of the Nd(III) complexes showed that excitation into ligand-centred –* transitions result in the characteristic near-infrared luminescence from Nd(III) at 1060 nm.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '57', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b618258e', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '565' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '565', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '565', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '565', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '565', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '44', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'A closed molecular cube and an open book: two different products from assembly of the same metal salt and bridging ligand ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/65', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '23', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=b515296h', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '30', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '542-544', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '54', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1477-9226', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '44', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '565', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20060000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '16', 'number' => '4', 'rev_number' => '17', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '10', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'Reaction of the bis-bidentate bridging ligand L1 with Co(ClO4)2 or Zn(BF4)2 affords a mixture of complexes [M8(L1)12]X16 and [M6(L1)9]X12 having the same metal : ligand ratio: the former is a molecular cube with a metal ion at each vertex and a bridging ligand spanning each edge, whereas the latter has a metal framework like that of an open book containing cross-linked double helical metal–ligand subunits.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '10', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/b515296h', 'volume' => '2006', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1 Reviews: (a) G. F. Swiegers and T. J. Malefetse, Coord. Chem. Rev., 2002, 225, 91; (b) M. Fujita, M. Tominaga, A. Hori and B. Therrien, Acc. Chem. Res., 2005, 38, 369; (c) D. Fiedler, D. H. Leung, R. G. Bergman and K. N. Raymond, Acc. Chem. Res., 2005, 38, 349; (d) M. Yoshizawa and M. Fujita, Pure Appl. Chem., 2005, 77, 1107. 2 Representative recent examples:(a) M. Schweiger, T. Yamamoto, P. J. Stang, D. Blaser and R. Boese, J. Org. Chem., 2005, 70, 4861; (b) R. W. Saalfrank, B. Demleitner, H. Glaser, H. Maid, D. Bathelt, F. Hampel, W. Bauer and M. Teichert, Chem. Eur. J., 2002, 8, 2679; (c) J. K. Clegg, L. F. Lindoy, B. Moubaraki, K. S. Murray and J. McMurtrie, Dalton Trans., 2004, 2417; (d) A. V. Davis and K. N. Raymond, J. Am. Chem. Soc., 2005, 127, 7912; (e) K. Nakabayashi, M. Kawano and M. Fujita, Angew. Chem., Int. Ed., 2005, 44, 5322; (f) S. Karthikeyan and V. Ramamurthy, Tetrahedron Lett., 2005, 46, 4495; (g) D. J. Bray, L. L. Liao, B. Antonioli, K. Gloe, L. F. Lindoy, J. C. McMurtrie, G.Wei and X.Y. Zhang, Dalton Trans., 2005, 2082; (h) I.M.Muller andD. Moller, Angew. Chem., Int. Ed., 2005, 44, 2969; (i) T. Haino,M. Kobayashi, M. Chikaraishi and Y. Fukazawa, Chem. Commun., 2005, 2321. 3 B. Hasenknopf, J.-M. Lehn, B. O. Kneisel, G. Baum and D. Fenske, Angew. Chem., Int. Ed. Engl., 1996, 35, 1838; B. Hasenknopf, J.-M. Lehn, N. Boumidiene, A. Dupont-Gervais, A. Van Dorsselaer, B. Kneisel and D. Fenske, J. Am. Chem. Soc., 1997, 119, 10956. 4 M. Scherer, D. L. Caulder, D.W. Johnson and K. N. Raymond, Angew. Chem., Int. Ed., 1999, 38, 1588; M. Albrecht, I. Janser, J. Runsink, G. Raabe, P.Weis and R. Frohlich, Angew. Chem., Int. Ed., 2004, 43, 6662. 5 S. J. Park,D. M. Shin, S. Sakamoto, K. Yamaguchi, Y.K. Chung,M. S. Lah and J. I. Hong, Chem. Eur. J., 2004, 11, 235. 6 G. Baum, E. C. Constable, D. Fenske, C. E. Housecroft and T. Kulke, Chem. Commun., 1999, 195; F. Tuna, J. Hamblin, A. Jackson, G. Clarkson, N.W. Alcock andM. J. Hannon, Dalton Trans., 2003, 2141; C. S. Campos-Fernandez, B. L. Schottel, H. T. Chifotides, J. K. Bera, J. Basca, J. M. Koomen, D. H. Russell and K. R. Dunbar, J. Am. Chem. Soc., 2005, 127, 12909. 7 J. R. Nitschke and J.-M. Lehn, Proc. Natl. Acad. Sci. USA, 2003, 100, 11970. 8 J. S. Fleming, K.L. V. Mann, C.-A. Carraz, E. Psillakis, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Angew. Chem., Int. Ed., 1998, 37, 1279; R. L. Paul, Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Proc. Natl. Acad. Sci. USA, 2002, 99, 4883; R. L. Paul, Z. R. Bell, J. C. Jeffery, L. P. Harding, J. A. McCleverty and M. D. Ward, Polyhedron, 2003, 22, 781; R. L. Paul, S. P. Argent, J. C. Jeffery, L. P. Harding, J. M. Lynam and M. D. Ward, Dalton Trans., 2004, 3453; S. P. Argent, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding andM. D. Ward, Chem. Commun., 2005, 4647. 9 S. P.Argent,H.Adams, T.Riis-Johannessen, J. C. Jeffery, L. P. Harding andM. D. Ward, J. Am. Chem. Soc., DOI: 10.1021/ja056993o. 10 Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Angew. Chem., Int. Ed., 2002, 41, 2515. 11 Z. R. Bell, L. P. Harding and M.D.Ward, Chem. Commun., 2003, 2432. 12 Z. R. Bell, J. A. McCleverty andM. D.Ward, Aust. J. Chem., 2003, 56, 665. 13 S. Roche, C. Haslam, H. Adams, S. L. Heath and J. A. Thomas, Chem. Commun., 1998, 1681; K. K. Klausmeyer, T. B. Rauchfuss and S. R. Wilson, Angew. Chem., Int. Ed., 1998, 37, 1694; B. F. Abrahams, S. J. Egan and R. Robson, J. Am. Chem. Soc., 1999, 121, 3535; M. C. Hong, Y. J. Zhao, W. P. Su, R. Cao, M. Fujita, Z. Y. Zhou and A. S. C. Chan, J. Am. Chem. Soc., 2000, 122, 4819; E. J. Schelter, A. V. Prosvirin and K. R. Dunbar, J. Am. Chem. Soc., 2004, 126, 15004; Y. Liu, V. Kravtsov, R. D. Walsh, P. Poddar, H. Srikanth and M. Eddaoudi, Chem. Commun., 2004, 2806 and refs. therein.', 'date_year' => '2006', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '5477' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Turner', 'eprintid' => '5477', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'David R.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Batten', 'eprintid' => '5477', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Stuart R.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Lu', 'eprintid' => '5477', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Jinzhen', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '5477', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '31', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Heteroligand Molecular “Stirrups” Using Conformationally Flexible Ditopic Pyridyl?Pyrazolyl Ligands', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/54/77', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '44', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ic9010967', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'American Chemical Society', 'pagerange' => '7525-7527', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganic Chemistry', 'lastmod_second' => '31', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '00201669', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '31', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 8, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '5477', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '8', 'event_dates' => undef, 'fulltimestamp' => '20090800', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '15', 'number' => '16', 'rev_number' => '6', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '44', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '26', 'datestamp_day' => '26', 'abstract' => 'Heteroligand molecular “stirrups” form by the self-assembly of flexible ditopic ligands in combination with 4,4?-bipyridine and [(dppp)Pd)]2+. Crystallographic analysis shows that the ligands, bis[3-(4-pyridyl)pyrazolyl]-m-xylene (mXy4py3pz) and bis[4-(4-pyridyl)pyrazolyl]-p-xylene (pXy4py4pz) form complexes of the type [{(dppp)Pd}2(4,4?-bipy)(L)]·4OTf (1·4OTf and 2·4OTf, respectively) in the solid state, with remarkably similar structures considering the differences in substitution patterns between the two ligands. The self-assembly of both 14+ and 24+ is assisted by face-to-face ? interactions on the exterior of the macrocycle between the phenyl rings of the dppp ligands and the pyridyl groups of the ditopic ligands. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '44', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ic9010967', 'volume' => '48', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2009', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '16900' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1376896031', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Towns-Andrews', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Elizabeth', 'creators_id' => 'l.towns-andrews@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Mills', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Andrew', 'creators_id' => undef }, '7' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '7', 'creators_name_given' => 'Martina', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Moore', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Michelle', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Piela', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Sean A.F.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bullock', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Samantha', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '16900', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2013', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/16900/1/CRR_Manu.pdf|/style/images/fileicons/application_pdf.png;/16900/5/c3dt00090g.pdf', 'status_changed_second' => '37', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Synthesis of Ligands Containing N-oxide Donor Atoms and Their Assembly into Metallosupramolecular Structures.', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/69/00', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '38', 'refereed' => 'TRUE', 'contact_email' => 'c.r.rice@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C3DT00090G', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '1', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => undef, 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2013', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '6', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1477-9226', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '37', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 2, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '16900', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2014', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20130200', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '1', 'number' => undef, 'rev_number' => '13', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'red', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '10', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'A series of ligands that contain both N-donor and N-oxide donor atoms have been synthesised and ligands L5, L6, L7 and L8 contain, 4, 6, 5, and 6 donor atoms respectively. The smallest ligand L5 forms a mononuclear complex with Cu2+ ([Cu(L5)(ClO4)2(MeCN)]) whereas L6 and L7 form dinuclear double helicates with Ni2+ and Cu2+ respectively ([Ni2(L6)2]4+ and [Cu2(L7)2]4+ ). L8 forms a tetranuclear cyclic helicate upon reaction with Co2+ ([Co4(L8)4]8+) and in all cases the complexes are characterised by single-crystal X-ray diffraction and ESI-MS. The N-oxide units imparts flexibility in the ligand strand and where the unoxidised ligand strand forms a cyclic helicate, the incorporation of an N-oxide unit allows the formation of the dinuclear double helicate. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '10', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/C3DT00090G', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2013', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3467' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laye', 'eprintid' => '3467', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Rebecca H.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Buurma', 'eprintid' => '3467', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Niklaas J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Mullice', 'eprintid' => '3467', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lucy A.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3467', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '22', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Rhenium complexes of chromophore-appended dipicolylamine ligands: syntheses, spectroscopic properties, DNA binding and X-ray crystal structure', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/67', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '8', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b800999f', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '2140-2149', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'New Journal of Chemistry', 'lastmod_second' => '22', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1144-0546', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '22', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3467', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '12', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '8', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '26', 'datestamp_day' => '26', 'abstract' => 'The syntheses of two chromophore-appended dipicolylamine-derived ligands and their reactivity with pentacarbonylchlororhenium have been studied. The resultant complexes each possess the fac-Re(CO)3 core. The ligands L1 1-[bis(pyridine-2-ylmethyl)amino]methylpyrene and L2 2-[bis(pyridine-2-ylmethyl)amino]methylquinoxaline were isolated via a one-pot reductive amination in moderate yield. The corresponding rhenium complexes were isolated in good yields and characterised by 1H NMR, MS, IR and UV-Vis studies. X-Ray crystallographic data were obtained for fac-{Re(CO)3( L1)}(BF4), C34H26BF4N4O3Re: monoclinic, P2(1)/c, a = 18.327(2) , = 90.00°, b = 14.1537(14) , = 96.263(6)°, c = 23.511(3) , = 90.00°, 6062.4(11) 3, Z = 8. The luminescence properties of the ligands and complexes were also investigated, with the emission attributed to the appended chromophore in each case. Isothermal titration calorimetry suggests that fac-{Re(CO)3( L1)}(BF4) self-aggregates cooperatively in aqueous solution, probably forming micelle-like aggregates with a cmc of 0.18 mM. Investigations into the DNA-binding properties of fac-{Re(CO)3( L1)}(BF4) were undertaken and revealed that fac-{Re(CO)3( L1)}(BF4) binding to fish sperm DNA (binding constant 1.5 ± 0.2 × 105 M-1, binding site size 3.2 ± 0.3 base pairs) is accompanied by changes in the UV-Vis spectrum as typically observed for pyrene-based intercalators while the calorimetrically determined binding enthalpy (-14 ± 2 kcal mol-1) also agrees favourably with values as typically found for intercalators', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '8', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b800999f', 'volume' => '32', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1205' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1205', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '1205', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '1205', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1205', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1205', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => undef, 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '55', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Diastereoselective formation and optical activity of an M4L6 cage complex', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/12/05', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '44', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b509239f', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '4647-4649', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '55', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '55', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1205', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '8', 'number' => '37', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '44', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '24', 'datestamp_day' => '24', 'abstract' => 'A chiral bridging ligand affords a single diastereoisomer of tetrahedral M4L6 cage complex in which the optical rotation of each ligand is increased by a factor of 5 on coordination.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '44', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b509239f', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2005', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '567' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harrington', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Ross W.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '7' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '7', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '567', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'William', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '18', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Complexes of Ag(I), Hg(I) and Hg(II) with multidentate pyrazolyl-pyridine ligands: from mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/67', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '31', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=b607541j', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '30', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '4996-5013', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '22', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1477-9226', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '18', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '567', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20060000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '16', 'number' => '42', 'rev_number' => '20', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '51', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which AgAg contacts, as well as metal–ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal–metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral HgII4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '51', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/b607541j', 'volume' => '2006', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1 (a) D. L. Caulder and K. N. Raymond, Acc. Chem. Res., 1999, 32, 975; (b) G. F. Swiegers and T. J. Malefetse, Chem.–Eur. J., 2001, 7, 3637; (c) B. J. Holliday and C. A. Mirkin, Angew. Chem., Int. Ed., 2001, 40, 2022; (d) D. Philp and J. F. Stoddart, Angew. Chem., Int. Ed. Engl., 1996, 35, 1155; (e) S. Leininger, B. Olenyuk and P. J. Stang, Chem. Rev., 2000, 100, 853; (f) S. R. Seidel and P. J. Stang, Acc. Chem. Res., 2002, 35, 972; (g) L. K. Thompson, Coord. Chem. Rev., 2002, 233, 193; (h)M. Fujita, M. Tominaga, A. Hori and B. Therrien, Acc. Chem. Res., 2005, 38, 369; (i) D. Fiedler, D. H. Leung, R. G. Bergman and K. N. Raymond, Acc. Chem. Res., 2005, 38, 349. 2 J.-M. Lehn, A. Rigault, J. Siegel, J. Harrowfield, B. Chevrier and D. Moras, Proc. Natl. Acad. Sci. U. S. A., 1987, 84, 2565. 3 M.-T. Youinou, N. Rahmouni, J. Fischer and J. A. Osborn, Angew. Chem., Int. Ed. Engl., 1992, 31, 733. 4 T. Beissel, R. E. Powers and K. N. Raymond, Angew. Chem., Int. Ed. Engl., 1996, 35, 1084. 5 (a) J. S. Fleming,K. L. V.Mann, C.-A. Carraz, E. Psillakis, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Angew. Chem., Int. Ed., 1998, 37, 1279; (b) R. L. Paul, Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Proc. Natl. Acad. Sci. U. S. A., 2002, 99, 4883; (c) Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Angew. Chem., Int. Ed., 2002, 41, 2515; (d) Z. R. Bell, L. P. Harding and M. D. Ward, Chem. Commun., 2003, 2432; (e) R. L. Paul, S. P. Argent, J. C. Jeffery, L. P. Harding, J. M. Lynam and M. D. Ward, Dalton Trans., 2004, 3453; (f) S. P. Argent, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding and M. D. Ward, Chem. Commun., 2005, 4647; (g) S. P. Argent, H. Adams, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding and M. D. Ward, J. Am. Chem. Soc., 2006, 128, 72; (h) S. P. Argent, H. Adams, L. P. Harding and M. D. Ward, Dalton Trans., 2006, 542; (i) S. P. Argent, H. Adams, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding, O. Mamula andM. D.Ward, Inorg. Chem., 2006, in press; (j) S. P. Argent, H. Adams, L. P. Harding, T. Riis-Johannessen, J. C. Jeffery and M. D. Ward, New J. Chem., 2005, 29, 904. 6 Self-assembly mediated by Ag · · · Ag interactions: (a) J. Moussa, K. Boubekeur and H. Amouri, Eur. J. Inorg. Chem., 2005, 3808; (b) Q. L. Chu, D. C. Swenson and L. R. MacGillivray, Angew. Chem., Int. Ed., 2005, 44, 3569; (c) L. Dobrzanska, H. G. Raubenheimer and L. J. Barbour, Chem. Commun., 2005, 5050; (d) A. A. Mohamed, L. M. Perez and J. P. Fackler, Inorg. Chim. Acta, 2005, 258, 1657; (e) H. P. Zhang, Y. B. Wang, X. C. Huang, Y. Y. Lin and X. M. Chen, Chem.– Eur. J., 2005, 11, 552. 7 Hg· · · Hg interactions: C. E. Holloway and M. Melic, J. Organomet. Chem., 1995, 495, 1; A. J. Faville, W. Henderson, T. J. Mathieson and B. K. Nicholson, J. Organomet. Chem., 1999, 580, 363; X.Wang and L. Andrews, Inorg. Chem., 2004, 43, 7146; W.-Y. Wong, L. Liu and J.-X. Shi, Angew. Chem., Int. Ed., 2003, 42, 4064; W.-Y. Wong, K.-H. Choi, G.-L. Lu and Z. Lin, Organometallics, 2002, 21, 4475; K. R. Flower, V. J. Howard, S. Naguthney, R. G. Pritchard, J. E. Warren and A. T. McGown, Inorg. Chem., 2002, 41, 1907; W.-Y. Wong, G.-L. Liu, L. Li, J.-X. Shi and Z. Lin, Eur. J. Inorg. Chem., 2004, 2066. 8 L. Han and M. Hong, Inorg. Chem. Commun., 2005, 8, 406. 9 H. Nierengarten, J. Rojo, E. Leize, J.-M. Lehn and A. Van Dorsselaer, Eur. J. Inorg. Chem., 2002, 573. 10 (a) S. Tavacoli, T. A. Miller, R. L. Paul, J. C. Jeffery and M. D. Ward, Polyhedron, 2003, 22, 507; (b) B. Wu, W.-J. Zhang, S.-Y. Yu and X.-T. Wu, J. Chem. Soc., Dalton Trans., 1997, 1795; (c) S. P. Anthony and T. P. Radhakrishnan, Chem. Commun., 2004, 1058; (d) R. H. Wang, M. C. Hong, W. P. Su, Y. C. Liang, R. Cao, Y. J. Zhao and J. B. Weng, Inorg. Chim. Acta, 2001, 323, 139; (e) R. H. Wang, L. J. Xu, X. S. Li, Y. M. Li, Q. Shi, Z. Y. Zhou, M. C. Hong and A. S. C. Chan, Eur. J. Inorg. Chem., 2004, 1595; (f) K. Nomiya, S. Takahashi, R. Satomi, S. Nemoto, T. Takayama and M. Oda, Inorg. Chem., 2000, 39, 3301; (g) A. Erxleben, Inorg. Chem., 2001, 40, 2928; (h) E. Psillakis, J. C. Jeffery, J. A. McCleverty and M. D. Ward, J. Chem. Soc., Dalton Trans., 1997, 1645; (i) P. L. Caradoc Davies, L. R. Hanton and W. Henderson, J. Chem. Soc., Dalton Trans., 2001, 2749; (j) T. K. Ronson, H. Adams and M. D.Ward, Eur. J. Inorg. Chem., 2005, 4533; (k) C. M. Fitchett and P. J. Steel, Aust. J. Chem., 2006, 59, 19. 11 (a) X. Sun, D. W. Johnson, D. L. Caulder, K. N. Raymond and E. H. Wong, J. Am. Chem. Soc., 2001, 123, 2752; (b)A.M.Garcia-Deibe, J. S. Metalobos, M. Fondo, M. Vazquez and M. R. Bermejo, Inorg. Chim. Acta, 2004, 357, 2561; (c) X. Sun, D. W. Johnson, K. N. Raymond and E. H. Wong, Inorg. Chem., 2001, 40, 4504; (d) Y. P. Cai, C. Y. Su, C. L. Chen, Y. M. Li, B. S. Kang, A. S. C. Chan and W. Kaim, Inorg. Chem., 2003, 42, 163; (e) W. Schuh, H. Kopacka, K. Wurst and P. Peringer, Eur. J. Inorg. Chem., 2002, 2202; (f)M. Albrecht, I. Janser, H. Houjou and R. Frohlich, Chem.–Eur. J., 2004, 10, 2839; (g) M. Albrecht, Chem.–Eur. J., 1997, 3, 1466. 12 (a)A. J.Amoroso, J. C. Jeffery, P. L. Jones, J.A.McCleverty, E. Psillakis andM. D. Ward, J. Chem. Soc., Chem. Commun., 1995, 1475; (b) S. L. James, E. Lozano and M. Nieuwenhuyzen, Chem. Commun., 2000, 617; (c) D. J. Bray, L. L. Liao, B. Antonioli, K. Gloe, L. F. Lindoy, J. C. McMurtrie, G. Wei and X. Y. Zhang, Dalton Trans., 2005, 2082; (d) H.-K. Liu, W.-Y. Sun, D.-J. Ma, K.-B. Yu and W.-X. Tang, Chem. Commun., 2000, 591; (e) S. Hiraoka, Y. Kubota and M. Fujita, Chem. Commun., 2000, 1509; (f) Y. Bretonni`ere, M. Mazzanti, R.Wietzke and J. P´ecaut, Chem. Commun., 2000, 1543; (g) E. Lindner,M. Khanfar and M. Steimann, Eur. J. Inorg. Chem., 2001, 2411; (h) W.-Y. Sun, J. Fan, T. Okamura, J. Xie, K.-B. Yu and N. Ueyama, Chem.–Eur. J., 2001, 40, 2557; (i) A. Ikeda, H. Udzu, Z. Zhong, S. Shinkai, S. Sakamoto and K. Yamaguchi, J. Am. Chem. Soc., 2001, 123, 3872. 13 (a) C.-Y. Su, B.-S. Kang, C.-X. Du, Q.-C. Yang and T. C. W. Mak, Inorg. Chem., 2000, 39, 4843; (b) P.Miller, M. Nieuwenhuyzen, J. P. H. Charmant and S. L. James, CrystEngComm, 2004, 6, 408. 14 (a) C. J. Baylies, L. P. Harding, J. C. Jeffery, T. Riis-Johannessen and C. R. Rice, Angew. Chem., Int. Ed., 2004, 43, 4515; (b) D. Grdenic, B. Kamenar and A. Hergold-Brundic, Croat. Chim. Acta, 1979, 52, 339; (c) N.Masciocchi, G. A. Ardizzoia, A.Maspero, G. La Monica and A. Sironi, Inorg. Chem., 1999, 38, 3657. 15 (a) J. C. Dewan, D. L. Kepert and A. H. White, J. Chem. Soc., Dalton Trans., 1975, 490; (b) D. Taylor, Aust. J. Chem., 1977, 30, 2647; (c) K. Brodersen and H.-U. Hummel, in Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, 1st edn, 1987, vol. 5, p. 1047, . 16 (a)D. Bravo-Zhivotovskii, M.Yuzefovich, M. Bendikov, K. Klinkhammer and Y. Apeloig, Angew. Chem., Int. Ed., 1999, 39, 1100; (b) W. Frank and B. Dincher, Z. Naturforsch., 1987, 42b, 828; (c) R.Malleier, H. Kopacka, W. Schuh, K. Wurst and P. Peringer, Chem. Commun., 2001, 51. 17 M. L. McKee and M. Swart, Inorg. Chem., 2005, 44, 6975. 18 (a) G. B. Deacon, C. L. Raston, D. Tunaley and A. H. White, Aust. J. Chem., 1979, 32, 2195; (b) D. C. Apperley, W. Clegg, S. Coles, J. L. Coyle, N. Martin, B. Maubert, V. McKee and J. Nelson, J. Chem. Soc., Dalton Trans., 1999, 229. 19 (a) B. Soro, S. Stoccoro, G. Minghetti, A. Zucca, M. A. Cinellu, S. Gladiali, M. Manassero and M. Sansoni, Organometallics, 2005, 24, 53; (b) R. V. Parish, J. P. Wright and R. G. Pritchard, J. Organomet. Chem., 2000, 596, 165; (c) Y. J.Wu, S. Q. Huo, J. F. Gong, X. L. Cui, L. Ding, K. L. Ding, C. X. Du, Y. H. Liu and M. P. Song, J. Organomet. Chem., 2001, 637, 27; (d) C. W. Chan, S.-M. Peng and C.-M. Che, Inorg. Chem., 1994, 33, 3656; (e) E. C. Constable, T. A. Leese and D. A. Tocher, J. Chem. Soc., Chem. Commun., 1989, 570. 20 Representative examples of metallo-catenates: (a) A. M. L. Fuller, D. A. Leigh, P. J. Lusby, A. M. Z. Slawin and D. B. Walker, J. Am. Chem. Soc., 2005, 127, 12612; (b) L. Flamigni, A. M. Talarico, J.-C. Chambron, V. Heitz, M. Linke, N. Fujita and J.-P. Sauvage, Chem.– Eur. J., 2004, 10, 2689; (c) A. Livoreil, J.-P. Sauvage, N. Armaroli, V. Balzani, L. Flamigni and B. Ventura, J. Am. Chem. Soc., 1997, 119, 12114; (d) D. J. Cardenas and J.-P. Sauvage, Inorg. Chem., 1997, 36, 2777; C. O. Dietrich-Buchecker, J. Guilhem, A. K. Khemiss, J.-P.Kintzinger, C. Pascard and J.-P. Sauvage, Angew. Chem., Int. Ed. Engl., 1987, 26, 661; (e) A. Hori, K. Yamashita and M. Fujita, Angew. Chem., Int. Ed., 2004, 43, 5016; (f) A. Hori, K. Yamashita, T. Kusukawa, A. Akasaka, K. Biradha and M. Fujita, Chem. Commun., 2004, 1798; (g) C. Dietrich-Buchecker, B. Colasson, M. Fujita, A. Hori, N. Geum, S. Sakamoto, K. Yamaguchi and J.-P. Sauvage, J. Am. Chem. Soc., 2003, 125, 5717; (h) M. Fujita, Acc. Chem. Res., 1999, 32, 53; (i) J.-P. Collin, V. Heitz and J.-P. Sauvage, Top. Curr. Chem., 2005, 262, 29. 21 C. O. Dietrich-Buchecker, J.-P. Sauvage and J. P. Kintzinger, Tetrahedron Lett., 1983, 24, 5095. 22 A. J. Blake, C. O. Dietrich-Buchecker, T. I. Hyde, J.-P. Sauvage andM. Schr¨oder, J. Chem. Soc., Chem. Commun., 1989, 1663. 23 G. M. Sheldrick, SADABS version 2.10, University of G¨ ottingen, 2003. 24 G. M. Sheldrick, SHELXS-97 and SHELXL-97, University of G¨ ottingen, 1997.', 'date_year' => '2006', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '6352' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Felton', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Cara E.', 'creators_id' => 'c.e.felton@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Andrews', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Michael', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bullock', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Sam', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '7' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '7', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fennessy', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Rebecca V.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '6352', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '11', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '22', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Coumarin-based luminescent ligand that forms helicates with dicationic metal ions', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/63/52', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '15', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b913103e', 'succeeds' => undef, 'datestamp_month' => '11', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '10570-10573', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '34', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '22', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 12, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '6352', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20091200', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => undef, 'rev_number' => '8', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '18', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '23', 'datestamp_day' => '23', 'abstract' => 'The potentially hexadentate ligand L, which contains two terminal coumarin fluorophores, forms dinuclear double-stranded helicates with dicationic metal ions, giving species of the generic form [M2L2]4+. In solution the free ligand was fluorescent with emission attributed to the coumarin fluorophores (em = 437 nm). The luminescent properties of the corresponding dimetallic helicates complexes were examined and revealed that the Zn2+ complex demonstrates enhanced emission when compared to the parent ligand, whereas Co2+, Cu2+, Cd2+ and Hg2+ induce varying degrees of fluorescence quenching. In particular, comparative luminescence measurements at 77 K and room temperature showed that the quenching mechanism for [Cu2L2]4+ can be attributed to a photoinduced electron transfer. ESI-MS selectivity studies showed that in the presence of a mixture of metal dications no preference for any one metal ion was observed.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '18', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b913103e', 'volume' => '47', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2009', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '566' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '566', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '37', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'High-nuclearity homoleptic and heteroleptic coordination cages based on tetra-capped truncated tetrahedral and cuboctahedral metal frameworks ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/66', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '21', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2006/128/i01/abs/ja056993o.html', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '30', 'publisher' => 'American Chemical Society', 'pagerange' => '72-73', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '56', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '37', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 12, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '566', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20051200', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '16', 'number' => '1', 'rev_number' => '19', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '33', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'Two new types of coordination cage have been prepared and structurally characterized: [M16(-L1)24]X32 are based on a tetra-capped truncated tetrahedral core and have a bridging ligand L1 along each of the 24 edges; [M12(-L1)12(3-L2)4]X24 are based on a cuboctahedral core which is supported by a combination of face-capping ligands L2 and edge-bridging ligands L1. The difference between the two illustrates how combinations of ligands with different coordination modes can generate coordination cages which are not available using one ligand type on its own', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '33', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ja056993o', 'volume' => '128', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '(1) (a) Swiegers, G. F.; Malefetse, T. J. Coord. Chem. ReV. 2002, 225, 91. (b) Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B. Acc. Chem. Res. 2005, 38, 369. (c) Fiedler, D.; Leung, D. H.; Bergman, R. G.; Raymond, K. N. Acc. Chem. Res. 2005, 38, 349. (d) Schweiger, M.; Yamamoto, T.; Stang, P. J.; Blaser, D.; Boese, R. J. Org. Chem. 2005, 70, 4861. (2) (a) Caulder, D. L.; Powers, R. E.; Parac, T. N.; Raymond, K. N. Angew. Chem., Int. Ed. 1998, 37, 1840. (b) Argent, S. P.; Riis-Johannessen, T.; Jeffery, J. C.; Harding, L. P.; Ward, M. D. Chem. Commun. 2005, 4647 and references therein. (c) Saalfrank, R. W.; Demleitner, B.; Glaser, H.; Maid, H.; Bathelt, D.; Hampel, F.; Bauer, W.; Teichert, M. Chem. Eur. J. 2002, 8, 2679. (d) Clegg, J. K.; Lindoy, L. F.; Moubaraki, B.; Murray, K. S.; McMurtrie, J. C. Dalton Trans. 2004, 2417. (3) Bell, Z. R.; Harding, L. P.; Ward, M. D. Chem. Commun. 2003, 2432. (4) Bell, Z. R.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D. Angew. Chem., Int. Ed. 2002, 41, 2515. (5) (a) Amoroso, A. J.; Jeffery, J. C.; Jones, P. L.; McCleverty, J. A.; Thornton, P.; Ward, M. D. Angew. Chem., Int. Ed. Engl. 1995, 34, 1443. (b) Saalfrank, R. W.; Glaser, H.; Demleitner, B.; Hampel, F.; Chowdhry, M. M.; Schunemann, V.; Trautwein, A. X.; Vaughan, G. B. M.; Yeh, R.; Davis, A. V.; Raymond, K. N. Chem. Eur. J. 2002, 8, 493. (6) Hiraoka, S.; Kubota, Y.; Fujita, M. Chem. Commun. 2000, 1509. (7) Olenyuk, B.; Whiteford, J. A.; Fechtenko¨tter, A.; Stang, P. J. Nature 1999, 398, 796. (8) (a) Tominaga, M.; Suzuki, K.; Kawano, M.; Kusukawa, T.; Ozeki, T.; Sakamoto, S.; Yamaguchi, K.; Fujita, M. Angew. Chem., Int. Ed. Engl. 2004, 43, 5621. (b) Tominaga, M.; Suzuki, K.; Murase, T.; Fujita, M. J. Am. Chem. Soc. 2005, 127, 11950. (c) Eddaoudi, M.; Kim, J.; Wachter, J. B.; Chae, H. K.; O’Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 2001, 123, 4368. (d) Abrahams, B. F.; Egan, S. J.; Robson, R. J. Am. Chem. Soc. 1999, 121, 3535. JA056993O', 'date_year' => '2005', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '924' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '924', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '924', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Al-Rasbi', 'eprintid' => '924', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Nawal K.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '924', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '6', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '42', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Coordination Behaviour of Bis-Terdentate N-Donor Ligands: Double- and single-stranded helicates, mesocates, and cyclic oligomers ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/24', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '4', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/ejic.200700715', 'succeeds' => undef, 'datestamp_month' => '6', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Wiley - VCH Verlag GmbH & Co. KGaA', 'pagerange' => '4770-4780', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'European Journal of Inorganic Chemistry', 'lastmod_second' => '35', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1434-1948', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '42', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '924', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '30', 'rev_number' => '17', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '17', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '30', 'datestamp_day' => '30', 'abstract' => 'Three new ligands have been prepared in which two terdentate chelating pyrazolyl-bipyridine units are connected by a central aromatic spacer via methylene hinges: the spacers are o-phenylene (LPh), 2,6-pyridine-diyl (LPy) and 2,3-naphthalenediyl (Lnaph). The ligands act as potentially hexadentate bridging ligands, with the central pyridyl N atom of LPy not involved in coordination. The following complexes were prepared and structurally characterised: [M2(LPh)2][ClO4]4 (M = Ni, Cu), which are dinuclear double helicates; [Ag2(LPh)(MeCN)2][BF4]2, a dinuclear complex with an Ag···Ag bond in which the ligand adopts a helical twist around the pair of metal ions; [Ni2(LPy)2][BF4]4, an achiral mesocate with a box-like structure and a face-to-face arrangement of ligands; [Ag3(Lnaph)2](BF4)3, which contains a linear trinuclear array of AgI ions with the two ligands arranged in a shallow helical twist, each ligand spanning one terminal and the central metal ion; and [Cd6(Lnaph)6](ClO4)12, a cyclic hexanuclear helicate with a perchlorate anion in the central cavity. Both [Cu2(LPh)2][ClO4]4 and [Cd6(Lnaph)6](ClO4)12, which have architecturally similar bridging ligands, show evidence by electrospray mass spectrometry for formation of a range of cyclic oligomers in solution up to 11-mers for the CdII/Lnaph system.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '17', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1002/ejic.200700715', 'volume' => '2007', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '255' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1286973785', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Marshall', 'eprintid' => '255', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Valerie M.', 'creators_id' => 'v.m.marshall@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '255', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '255', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Gu', 'eprintid' => '255', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Y.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Elvin', 'eprintid' => '255', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'M.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '1', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2007', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/255/1/Laws_Structural_characterisation_of_a_perdeuteriomethylated.pdf', 'status_changed_second' => '14', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Structural characterisation of a perdeuteriomethylated exoploysaccharide by NMR spectroscopy: characterisation of the novel exopolysaccharide produced by Lactobacillus delbrueckii subsp. Bulgaricus EU23', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/02/55', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'restricted', 'lastmod_minute' => '43', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/S0008-6215(02)00354-3', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '13', 'publisher' => 'Elsevier', 'pagerange' => '61-67', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Carbohydrate Research', 'lastmod_second' => '30', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0008-6215', 'datestamp_hour' => undef, 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => undef, 'note' => 'UoA 18 (Chemistry) Copyright © 2007 Elsevier B.V. All rights reserved. ScienceDirect® is a registered trademark of Elsevier B.V. ', 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '255', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20030000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '1', 'rev_number' => '11', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '31', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '13', 'abstract' => 'The exopolysaccharide (EPS) from Lactobacillus delbrueckii subsp. bulgaricus EU23 was perdeuteriomethylated and the perdeuteriomethylated EPS (pdm-EPS) purified by elution from a C18 Sep-Pak cartridge. Both 1D and 2D NMR spectra were recorded for the pdm-EPS and these were interpreted to provide assignments for the individual 1H and 13C resonances of the sugar residues of the repeating unit. Using a combination of the results from monomer analysis and linkage analysis of the native EPS and the ROESY and HMBC NMR spectra of the pdm-EPS the following structure has been determined for the repeating unit: ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '12', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => undef, 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1016/S0008-6215(02)00354-3', 'volume' => '338', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => 'References 1. J. Delcour, T. Ferain, M. Deghorain, E. Palumbo and P. Hols Antonie Van Leeuwenhoek Int. J. General Molecular Microbiol. 76 (1999), p. 159. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 2. A. Laws, Y.C. Gu and V. Marshall Biotechnol. Adv. 19 (2001), p. 597. SummaryPlus | Full Text + Links | PDF (291 K) | View Record in Scopus | Cited By in Scopus 3. I.W. Sutherland Intern. Dairy J. 11 (2001), p. 663. SummaryPlus | Full Text + Links | PDF (199 K) | View Record in Scopus | Cited By in Scopus 4. L. De Vuyst and B. Degeest FEMS Microbiol. Rev. 23 (1999), p. 153. SummaryPlus | Full Text + Links | PDF (529 K) | View Record in Scopus | Cited By in Scopus 5. J. Cerning and V.M. Marshall Recent Res. Devel. Microbiol. 3 (1999), p. 195. 6. J. Cerning FEMS Microbiol. Rev. 87 (1990), p. 113. Abstract | Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 7. A. Ricciardi and F. Clementi Italian J. Food Sci. 12 (2000), p. 23. 8. B.R. Leeflang, E.J. Faber, P. Erbel and J.F.G. Vliegenthart J. Biotechnol. 77 (2000), p. 115. SummaryPlus | Full Text + Links | PDF (592 K) | View Record in Scopus | Cited By in Scopus 9. J.O. Duus, C.H. Gotfredsen and K. Bock Chem. Rev. 100 (2000), p. 4589. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 10. G.J. Gerwig, J.P. Kamerling and J.F.G. Vliegenthart Carbohydr. Res. 62 (1978), p. 349. Abstract | Abstract + References | PDF (523 K) 11. K. Stellner, H. Saito and S.I. Hakomori Arch. Biochem. Biophys. 155 (1973), p. 464. Abstract | Full Text + Links | PDF (682 K) | View Record in Scopus | Cited By in Scopus 12. D.P. Sweet, R.H. Shapiro and P. Albersheim Carbohydr. Res. 40 (1975), p. 217. Abstract | Abstract + References | PDF (622 K) 13. J. Cerning, C. Bouillanne, M.J. Desmazeaud and M. Landon Biotechnol. Lett. 8 (1986), p. 625. Full Text via CrossRef 14. S.J.F. Vincent, E.J. Faber, J.R. Neeser, F. Stingele and J.P. Kamerling Glycobiology 11 (2001), p. 131. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 15. A.L. Kvernheim Acta Chem. Scand. Ser. B-Org. Chem. Biochem. 41 (1987), p. 150. 16. I. Ciucanu and F. Kerek Carbohydr. Res. 131 (1984), p. 209. Abstract | Abstract + References | PDF (498 K) 17. P.J. Harris, R.J. Henry, A.B. Blakeney and B.A. Stone Carbohydr. Res. 127 (1984), p. 59. Abstract | Abstract + References | PDF (1002 K) | View Record in Scopus | Cited By in Scopus 18. Elvin, M.; Ph.D. Thesis, School of Applied Sciences, Huddersfield University, Huddersfield, 2001, pp. 129–132. 19. A.J. Mort, S. Parker and M.S. Kuo Anal. Biochem. 133 (1983), p. 380. Abstract | Full Text + Links | PDF (350 K) | View Record in Scopus | Cited By in Scopus 20. I.W. Sutherland Annu. Rev. Microbiol. 39 (1985), p. 243. View Record in Scopus | Cited By in Scopus ', 'date_year' => '2003', 'status_changed_hour' => '18', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '5478' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Turner', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'David R.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baker', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Murray V.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Lu', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Jinzhen', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Byrne', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay T.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Batten', 'eprintid' => '5478', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Stuart R.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '27', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Octapi Interactions: Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold ? Interactions', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/54/78', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '50', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ja9041912', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'American Chemical Society', 'pagerange' => '10372-10373', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '27', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '27', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 8, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '5478', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '8', 'event_dates' => undef, 'fulltimestamp' => '20090800', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '15', 'number' => '30', 'rev_number' => '8', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '50', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '26', 'datestamp_day' => '26', 'abstract' => 'An unprecedented 2.5 nm array of ? interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '50', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1021/ja9041912', 'volume' => '131', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2009', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3461' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '3461', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '3461', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Westcott', 'eprintid' => '3461', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Aleema', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rizkallah', 'eprintid' => '3461', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Pierre', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3461', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '58', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Self-Assembly of a 3-D Triply Interlocked Chiral [2]Catenane', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/61', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '46', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 12, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ja8002149', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'American Chemical Society', 'pagerange' => '2950-2951', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '45', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '58', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3461', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080312', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '10', 'rev_number' => '12', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '25', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'A tripodal cyclotriveratrylene-based ligand with chelating 2,2‘-bipyridine arms self-assembles with either Zn(NO3)2 or Co(NO3)2 to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '25', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1021/ja8002149', 'volume' => '130', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3466' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Russo', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Luca', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Faust', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Thomas B.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Tidmarsh', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Ian S.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '3466', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'William', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '13', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Octanuclear Cubic Coordination Cages', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/66', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '47', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 15, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ja805605y', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'American Chemical Society', 'pagerange' => '15167-15175', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '17', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '13', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3466', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20081015', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '45', 'rev_number' => '12', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '37', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'Two new bis-bidentate bridging ligands have been prepared, Lnaph and Lanth, which contain two chelating pyrazolyl-pyridine units connected to an aromatic spacer (naphthalene-1,5-diyl and anthracene-9,10-diyl respectively) via methylene connectors. Each of these reacts with transition metal dications having a preference for octahedral coordination geometry to afford {M8L12}16+ cages (for Lanth, M = Cu, Zn; for Lnaph, M = Co, Ni, Cd) which have an approximately cubic arrangement of metal ions with a bridging ligand spanning each of the twelve edges, and a large central cavity containing a mixture of anions and/or solvent molecules. The cages based on Lanth have two cyclic helical {M4L4} faces, of opposite chirality, connected by four additional Lanth ligands as “pillars”; all metal centers have a meridional tris-chelate configuration. In contrast the cages based on Lnaph have (noncrystallographic) S6 symmetry, with a diagonally opposite pair of corners having a facial tris-chelate configuration with the other six being meridional. An additional significant difference between the two types of structure is that the cubes containing Lanth do not show significant interligand aromatic stacking interactions. However, in the cages based on Lnaph, there are six five-membered stacks of aromatic ligand fragments around the periphery, each based on an alternating array of electron-rich (naphthyl) and electron-deficient (pyrazolyl-pyridine, coordinated to M2+) aromatic units. A consequence of this is that the cages {M8(Lnaph)12}16+ retain their structural integrity in polar solvents, in contrast to the cages {M8(Lanth)12}16+ which dissociate in polar solvents. Consequently, the cages {M8(Lnaph)12}16+ give NMR spectra in agreement with the symmetry observed in the solid state, and their fluorescence spectra (for M = Cd) display (in addition to the normal naphthalene-based ???* fluorescence) a lower-energy exciplex-like emission feature associated with a naphthyl ? pyrazolyl-pyridine charge-transfer excited state arising from the ?-stacking between ligands around the cage periphery', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '37', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1021/ja805605y', 'volume' => '130', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '13204' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1349876314', 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Simon JA', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Cox', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Nicola M', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jones', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Jennifer E.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '13204', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Harry', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '4', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/13204/1/LPH_Dalton_1_Repository.pdf', 'status_changed_second' => '20', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Probing solution behaviour of metallosupramolecular complexes using pyrene fluorescence', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/32/04', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '38', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C1DT11831E ', 'succeeds' => undef, 'datestamp_month' => '4', 'commentary' => undef, 'lastmod_day' => '15', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '1568-1573', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '4', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '20', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 4, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '13204', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2012', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '11', 'event_dates' => undef, 'fulltimestamp' => '20120400', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '1', 'number' => '5', 'rev_number' => '13', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '30', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'A new method for assessing the topology of metallosupramolecular assemblies using pyrene-appended ligands is reported. Two potentially tetradentate ligands containing one (L1) and two (L2) terminal pyrene moieties were synthesised and their complexes with Cu+ and Cd2+ were characterised. Photophysical measurements demonstrate that in [Cu2(L1)2]2+, [CdL1]2+ and [Cu2(L2)2]2+ the emission spectra are dominated by monomeric emission but in the cadmium complex of L2 (where the pyrene units are in close proximity) a quenching of the luminescence coupled with weak emission at 540 nm is indicative of excimer formation.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '30', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/C1DT11831E ', 'volume' => '41', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2012', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '13143' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1332415462', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '13143', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '13143', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Sutton', 'eprintid' => '13143', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Cara E.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '13143', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '13143', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '', 'status_changed_second' => '44', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Allosteric Effects in a Ditopic Ligand Containing Bipyridine and Tetra-aza-crown Donor Units', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/31/43', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '40', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/chem.201103217', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '22', 'publisher' => 'Wiley', 'pagerange' => '3464-3467', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemistry - A European Journal', 'lastmod_second' => '44', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0947-6539', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '44', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '13143', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2012', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20120300', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '12', 'rev_number' => '7', 'edit_lock_user' => '116', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '40', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '22', 'abstract' => undef, 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '40', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/chem.201103217', 'volume' => '18', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2012', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '4157' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bell', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Zoe R.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'McCleverty', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Jon A.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Paul', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Rowena L.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '4157', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '5', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '4', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Complexes of a bis-bidentate ligand with d10 ions: a mononuclear complex with Ag(I), and a tetrahedral cage complex with Zn(II) which encapsulates a fluoroborate anion', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/41/57', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '1', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/S0277-5387(02)01410-9', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '5', 'publisher' => 'Pergamon', 'pagerange' => '781-787', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Polyhedron', 'lastmod_second' => '4', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '02775387', 'datestamp_hour' => '13', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '4', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '4157', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '5', 'event_dates' => undef, 'fulltimestamp' => '20030300', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '13', 'number' => '5', 'rev_number' => '10', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '1', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'Complexes of the bis-bidentate ligand 2,3-bis[{3-(2-pyridyl)-pyrazol-1-yl}methyl]naphthalene (L2) with Ag(I) and Zn(II) have been prepared and structurally characterised. In [Ag(L2)][ClO4] both bidentate pyrazolyl–pyridine arms of L2 interact with the same Ag(I) centre, which has two short Ag---N bonds and two much longer, weaker interactions such that the coordination is best described as linear and bidentate. In contrast, in [Zn4(L2)6(BF4)][BF4]7 the ligands L2 act as bis-bidentate bridges; the structure consists of a tetrahedral cage of Zn(II) ions with a bridging ligand L2 along each of the six edges. The cavity at the centre of this three-dimensional tetrahedral cage accommodates a tetrafluoroborate anion which is completely encapsulated, and inverted with respect to the Zn4 tetrahedron. The F atoms of this encapsulated anion are involved in close F---HC contacts with parts of the bridging ligands. 11B and 19F NMR spectra show that the encapsulated anion does not exchange with free tetrafluoroborate anions in MeCN solution, even up to 70 °C.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '1', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1016/S0277-5387(02)01410-9', 'volume' => '22', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2003', 'status_changed_hour' => '13', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '254' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1286973730', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Marshall', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Valerie M.', 'creators_id' => 'v.m.marshall@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Maqsood', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Mohammed', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Gu', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Y.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hernandez', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Y.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'McLay', 'eprintid' => '254', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'N.', 'creators_id' => 'n.mclay@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '1', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2007', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/254/1/Laws_Structural_characterisation_of_the_highly.pdf', 'status_changed_second' => '12', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Structural characterisation of the highly branched exopolysaccharide produced by Lactobacillus delbrueckii subsp. Bulgaricus NCFB2074', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/02/54', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'restricted', 'lastmod_minute' => '42', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/j.carres.2005.01.038', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '13', 'publisher' => 'Elsevier', 'pagerange' => '1107-1111', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Carbohydrate Research', 'lastmod_second' => '43', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0008-6215', 'datestamp_hour' => undef, 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => undef, 'note' => 'UoA 18 (Chemistry) Copyright © 2007 Elsevier B.V. All rights reserved. ScienceDirect® is a registered trademark of Elsevier B.V. ', 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '254', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '6', 'rev_number' => '12', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '31', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '13', 'abstract' => 'Lactobacillus delbrueckii subsp. bulgaricus NCFB2074 when grown in skimmed milk secretes a highly branched exopolysaccharide. The exopolysaccharide has a heptasaccharide repeat unit and is composed of glucose and galactose in the molar ratio 3:4. Using chemical techniques and 1D and 2D NMR spectroscopy the polysaccharide has been shown to possess the following repeat unit structure:', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '12', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => undef, 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1016/j.carres.2005.01.038', 'volume' => '340', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1 I.W. Sutherland, Adv. Microbiol. Physiol. 8 (1972), pp. 143–213. View Record in Scopus | Cited By in Scopus 2 I.W. Sutherland, Microbial EPS Synthesis in Surface Carbohydrate of the Prokaryotic Cell, Academic Press, London (1977). 3 I.W. Sutherland, Annu. Rev. Microbiol. 39 (1985), pp. 243–270. View Record in Scopus | Cited By in Scopus 4 I.W. Sutherland, Carbohydr. Polym. 38 (1999), pp. 319–328. SummaryPlus | Full Text + Links | PDF (133 K) | View Record in Scopus | Cited By in Scopus 5 L. De Vuyst, M. Zamfir, F. Mozzi, T. Adriany, V. Marshall, B. Degeest and F. Vaningelgem, Int. Dairy J. 13 (2003), pp. 707–717. SummaryPlus | Full Text + Links | PDF (286 K) | View Record in Scopus | Cited By in Scopus 6 V.M. Marshall and H.L. Rawson, Int. J. Food Sci. Technol. 34 (1999), pp. 137–143. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 7 M. Kleerebezem, R. van Kranenburg, R. Tuinier, I.C. Boels, P. Zoon, E. Looijesteijn, J. Hugenholtz and W.M. de Vos, Antonie Van Leeuwenhoek 76 (1999), pp. 357–365. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 8 V.M. Marshall, H. Dunn, M. Elvin, N. McLay, Y. Gu and A.P. Laws, Carbohydr. Res. 331 (2001), pp. 413–422. SummaryPlus | Full Text + Links | PDF (300 K) | View Record in Scopus | Cited By in Scopus 9 T. Doco, J.M. Wieruszeski, B. Fournet, D. Carcano, P. Ramos and A. Loones, Carbohydr. Res. 198 (1990), pp. 313–321. Abstract | Abstract + References | PDF (576 K) | View Record in Scopus | Cited By in Scopus 10 J. Lemoine, F. Chirat, J.M. Wieruszeski, G. Strecker, N. Favre and J.R. Neeser, Appl. Environ. Microbiol. 63 (1997), pp. 3512–3518. View Record in Scopus | Cited By in Scopus 11 V.M. Marshall, A.P. Laws, Y. Gu, F. Levander, P. Radstrom, L. De Vuyst, B. Degeest, F. Vaningelem, H. Dunn and M. Elvin, Lett. Appl. Microbiol. 32 (2001), pp. 433–437. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 12 S.J.F. Vincent, E.J. Faber, J.R. Neeser, F. Stingele and J.P. Kamerling, Glycobiology 11 (2001), pp. 131–139. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 13 E.J. Faber, M.J. van den Haak, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 331 (2001), pp. 173–182. SummaryPlus | Full Text + Links | PDF (182 K) | View Record in Scopus | Cited By in Scopus 14 L. Navarini, A. Abatangelo, C. Bertocchi, E. Conti, M. Bosco and F. Picotti, Int. J. Biol. Macromol. 28 (2001), pp. 219–226. SummaryPlus | Full Text + Links | PDF (158 K) | View Record in Scopus | Cited By in Scopus 15 E.J. Faber, D.J. van Haaster, J.P. Kamerling and J.F.G. Vliegenthart, Eur. J. Biochem. 269 (2002), pp. 5590–5598. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 16 W.A. Bubb, T. Urashima, R. Fujiwara, T. Shinnai and H. Ariga, Carbohydr. Res. 301 (1997), pp. 41–50. SummaryPlus | Full Text + Links | PDF (852 K) | View Record in Scopus | Cited By in Scopus 17 Z.N. Yang, M. Staaf, E. Huttunen and G. Widmalm, Carbohydr. Res. 329 (2000), pp. 465–469. SummaryPlus | Full Text + Links | PDF (90 K) | View Record in Scopus | Cited By in Scopus 18 Y. Yamamoto, T. Nunome, R. Yamauchi, K. Kato and Y. Sone, Carbohydr. Res. 275 (1995), pp. 319–332. Abstract | Abstract + References | PDF (722 K) | View Record in Scopus | Cited By in Scopus 19 F. Stingele, J. Lemoine and J.R. Neeser, Carbohydr. Res. 302 (1997), pp. 197–202. Abstract | Abstract + References | PDF (511 K) | View Record in Scopus | Cited By in Scopus 20 Y. Yamamoto, S. Murosaki, R. Yamauchi, K. Kato and Y. Sone, Carbohydr. Res. 261 (1994), pp. 67–78. Abstract | Abstract + References | PDF (765 K) | View Record in Scopus | Cited By in Scopus 21 M. Staaf, G. Widmalm, Z.N. Yang and E. Huttunen, Carbohydr. Res. 291 (1996), pp. 155–164. SummaryPlus | Full Text + Links | PDF (566 K) | View Record in Scopus | Cited By in Scopus 22 M. Staaf, Z.N. Yang, E. Huttunen and G. Widmalm, Carbohydr. Res. 326 (2000), pp. 113–119. SummaryPlus | Full Text + Links | PDF (138 K) | View Record in Scopus | Cited By in Scopus 23 G.W. Robijn, J.R. Thomas, H. Haas, D.J.C. Vandenberg, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 276 (1995), pp. 137–154. Abstract | Abstract + References | PDF (911 K) | View Record in Scopus | Cited By in Scopus 24 G.W. Robijn, R.G. Gallego, D.J.C. vandenBerg, H. Haas, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 288 (1996), pp. 203–218. Abstract | Abstract + References | PDF (724 K) | View Record in Scopus | Cited By in Scopus 25 E.J. Faber, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 331 (2001), pp. 183–194. SummaryPlus | Full Text + Links | PDF (294 K) | View Record in Scopus | Cited By in Scopus 26 M. Gruter, B.R. Leeflang, J. Kuiper, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 239 (1993), pp. 209–226. Abstract | Abstract + References | PDF (1121 K) | View Record in Scopus | Cited By in Scopus 27 G.W. Robijn, H.L.J. Wienk, D.J.C. vandenBerg, H. Haas, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 285 (1996), pp. 129–139. SummaryPlus | Full Text + Links | PDF (738 K) | View Record in Scopus | Cited By in Scopus 28 M.R. Van Calsteren, C. Pau-Roblot, A. Begin and D. Roy, Biochem. J. 363 (2002), pp. 7–17. Full Text via CrossRef | View Record in Scopus | Cited By in Scopus 29 C. Vanhaverbeke, C. Bosso, P. Colin-Morel, C. Gey, L. Gamar-Nourani, K. Blondeau, J.M. Simonet and A. Heyraud, Carbohydr. Res. 314 (1998), pp. 211–220. SummaryPlus | Full Text + Links | PDF (260 K) | View Record in Scopus | Cited By in Scopus 30 W.H.M. van Casteren, P. de Waard, C. Dijkema, H.A. Schols and A.G.J. Voragen, Carbohydr. Res. 327 (2000), pp. 411–422. SummaryPlus | Full Text + Links | PDF (249 K) | View Record in Scopus | Cited By in Scopus 31 M. Gruter, B.R. Leeflang, J. Kuiper, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 231 (1992), pp. 273–291. Abstract | Abstract + References | PDF (1137 K) | View Record in Scopus | Cited By in Scopus 32 H. Nakajima, T. Hirota, T. Toba, T. Itoh and S. Adachi, Carbohydr. Res. 224 (1992), pp. 245–253. Abstract | Abstract + References | PDF (596 K) | View Record in Scopus | Cited By in Scopus 33 R. van Kranenburg, van Swam II, J.D. Marugg, M. Kleerebezem and W.M. de Vos, J. Bacteriol. 181 (1999), pp. 338–340. View Record in Scopus | Cited By in Scopus 34 Z.N. Yang, E. Huttunen, M. Staaf, G. Widmalm and H. Tenhu, Int. Dairy J. 9 (1999), pp. 631–638. SummaryPlus | Full Text + Links | PDF (242 K) | View Record in Scopus | Cited By in Scopus 35 W.H.M. van Casteren, C. Dijkema, H.A. Schols, G. Beldman and A.G.J. Voragen, Carbohydr. Res. 324 (2000), pp. 170–181. SummaryPlus | Full Text + Links | PDF (298 K) | View Record in Scopus | Cited By in Scopus 36 G.J. Gerwig, J.P. Kamerling and J.F.G. Vliegenthart, Carbohydr. Res. 62 (1978), pp. 349–357. Abstract | Abstract + References | PDF (523 K) 37 K. Stellner, H. Saito and S.I. Hakomori, Arch. Biochem. Biophys. 155 (1973), pp. 464–472. Abstract | Full Text + Links | PDF (682 K) | View Record in Scopus | Cited By in Scopus 38 D.P. Sweet, R.H. Shapiro and P. Albersheim, Carbohydr. Res. 40 (1975), pp. 217–225. Abstract | Abstract + References | PDF (622 K) ', 'date_year' => '2005', 'status_changed_hour' => '18', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3459' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '3459', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '3459', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '3459', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3459', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '7', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Star-Burst Prisms with Cyclotriveratrylene-Type Ligands: A [Pd6L8]12+ Stella Octangular Structure', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/59', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '44', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 3, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/anie.200703903', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Wiley - VCH Verlag GmbH & Co. KGaA', 'pagerange' => '9086-9088', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Angewandte Chemie International Edition', 'lastmod_second' => '48', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14337851', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '7', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 12, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3459', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20071203', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '47', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '51', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => undef, 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '51', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/anie.200703903', 'volume' => '46', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '18203' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1378210966', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Cross', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Jasmine M.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Cooke', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'David J.', 'creators_id' => 'd.j.cooke@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fennessy', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Rebecca V.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Slater', 'eprintid' => '18203', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Christopher', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '9', 'editors_name_honourific' => undef, 'admin_note' => 'Emailed for PP 2/9/13', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2013', 'fileinfo' => '', 'status_changed_second' => '1', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Steric control of the formation of dinuclear double helicate and dinuclear meso-helicate assemblies', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/82/03', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '35', 'refereed' => 'TRUE', 'contact_email' => 'd.j.cooke@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => 14, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C3CC44611E ', 'succeeds' => undef, 'datestamp_month' => '9', 'commentary' => undef, 'lastmod_day' => '3', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '7785-7787', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2013', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '1', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '12', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '1', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 9, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '18203', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2013', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20130914', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '71', 'rev_number' => '7', 'edit_lock_user' => '6', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '35', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '3', 'datestamp_day' => '3', 'abstract' => undef, 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '35', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/C3CC44611E ', 'volume' => '49', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2013', 'status_changed_hour' => '12', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '178' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1294835129', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Page', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Michael I.', 'creators_id' => 'm.i.page@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ahmed', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Naveed', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Tsang', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'W.Y.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Wood', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'J. Matthew', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hinchliffe', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Paul S.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '178', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '1', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2007', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/178/1/PageDifferent.pdf', 'status_changed_second' => '36', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Different transition-state structures for the reactions of ?-lactams and analogous ?-sultams with serine ?-lactamases ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/01/78', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'restricted', 'lastmod_minute' => '25', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/ja056124z', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '12', 'publisher' => 'American Chemical Society', 'pagerange' => '17556-17564', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '55', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => undef, 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => undef, 'note' => 'UoA 18 (Chemistry) © 2005 American Chemical Society', 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '178', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2011', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '1', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '49', 'rev_number' => '470', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '29', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '14', 'abstract' => '?-Sultams are the sulfonyl analogues of ?-lactams, and N-acyl ?-sultams are novel inactivators of the class C ?-lactamase of Enterobacter cloacaeP99. They sulfonylate the active site serine residue to form a sulfonate ester which subsequently undergoes C-O bond fission and formation of a dehydroalanine residue by elimination of the sulfonate anion as shown by electrospray ionization mass spectroscopy. The analogous N-acyl ?-lactams are substrates for ?-lactamase and undergo enzyme-catalyzed hydrolysis presumably by the normal acylation-deacylation process. The rates of acylation of the enzyme by the ?-lactams, measured by the second-order rate constant for hydrolysis, kcat/ Km, and those of sulfonylation by the ?-sultams, measured by the second-order rate constant for inactivation, ki , both show a similar pH dependence to that exhibited by the ?-lactamase-catalyzed hydrolysis of ?-lactam antibiotics. Electronwithdrawing groups in the aryl residue of the leaving group of N-aroyl ?-lactams increase the rate of alkaline hydrolysis and give a Bronsted ?lg of -0.55, indicative of a late transition state for rate-limiting formation of the tetrahedral intermediate. Interestingly, the corresponding Bronsted ?lg for the ?-lactamase-catalyzed hydrolysis of the same substrates is -0.06, indicative of an earlier transition state for the enzyme-catalyzed reaction. By contrast, although the Bronsted ?lg for the alkaline hydrolysis of N-aroyl ?-sultams is -0.73, similar to that for the ?-lactams, that for the sulfonylation of ?-lactamase by these compounds is -1.46, compatible with significant amide anion expulsion/S-N fission in the transition state. In this case, the enzyme reaction displays a later transition state compared with hydroxide-ion-catalyzed hydrolysis of the ?-sultam.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => undef, 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ja056124z', 'volume' => '127', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1. Waley, S. G. In The Chemistry of -Lactams; Page, M. I., Ed., Blackie: Glasgow, 1992; pp 198-226; Frère, J.-M. Mol. Microbiol. 1995, 16, 385-395. [Medline] 2. Payne, D. J. J. Med. Microbiol. 1993, 39, 93-99; [ChemPort] [Medline] Nordmann, P.; Mariotte, S.; Naas, T.; Labia, R.; Nicolas, M. H. Antimicrob. Agents Chemother. 1993, 37, 939-946; [ChemPort] [Medline] Naas. T.; Vandel, L.; Sougakoff, W.; Livermore, D. M.; Nordmann, P. Antimicrob. Agents Chemother. 1994, 38, 1262-1270. [Medline] 3. Bush, K.; Jacoby, G. A.; Medeiros, A. A. Antimicrob. Agents Chemother. 1995, 39, 1211-1233; [ChemPort] [Medline] Rasmussen, B. A.; Bush, K. Antimicrob. Agents Chemother. 1997, 41, 223-232; [ChemPort] [Medline] http://www.lahey.org/studies/ webt.asp. 4. Hechler, U.; Van den Weghe, M.; Martin, H. H.; Frère, J.-M. J. Gen. Microbiol. 1989, 135, 1275-1290. [ChemPort] [Medline] 5. Page, M. I.; Laws, A. P. Chem. Commun. 1998, 1609-1617. [ChemPort] [CrossRef] 6. Galleni, M.; Lamotte-Brasseur, J.; Rossolini, G. M.; Spencer, J.; Dideberg, O.; Frère, J.-M. Antimicrob. Agents Chemother. 2001, 45, 660-663. [ChemPort] [Medline] [CrossRef] 7. Kelly, J. A.; Dideberg, O.; Charlier, P.; Wery, J. P.; Libert, M.; Moews, P. C.; Knox, J. R.; Duez, C.; Fraipont, CL.; Joris, B.; Dusart, J.; Frère, J.-M.; Ghuysen, J. M. Science 1986, 231, 1429-1431; [ChemPort] [Medline] Samraoui, B.; Sutton, B. J.; Todd, R. J.; Artymiuk, P. J.; Waley, S. G.; Phillips, D. C. Nature 1986, 320, 378-380; [ChemPort] [Medline] Knox, J. R.; Moews, P. C. J. Mol. Biol. 1991, 220, 435-455; Moews, P. C.; Knox, J. R.; Dideberg, O.; Charlier, P.; Frère, J.-M. Proteins 1990, 7, 156-171; [ChemPort] [Medline] Herzberg, O.; Moult, J. Science 1987, 236, 694-701; [ChemPort] [Medline] Herzberg, O. J. Mol. Biol. 1991, 217, 701-719; [CrossRef] Dideberg, O.; Charlier, P.; Wéry, J.-P.; Dehottay, P.; Dusart, J.; Erpicum, T.; Frère, J.-M.; Ghuysen, J.-M. Biochem. J. 1987, 245, 911-913; [ChemPort] [Medline] Lamotte-Brasseur, J.; Dive, G.; Dideberg, O.; Charlier, P.; Frère, J.-M.; Ghuysen, J.-M.; Biochem. J. 1991, 279, 213-221; [ChemPort] [Medline] Jelsch, C.; Mourey, L.; Masson, J.-M.; Samama, J.-P. Proteins 1993, 16, 364-383. [ChemPort] [Medline] 8. Oefner, C.; D'Arcy, A.; Daly, J. J.; Gubernator, K.; Charnas, R. L.; Heinze, I.; Hubschwerlen, C.; Winkler, F. K. Nature 1990, 343, 284-288; [ChemPort] [Medline] [CrossRef] Lobkovsky, E.; Moews, P. C.; Liu, H.; Zhao, H.; Frère, J.-M.; Knox, J. R. Proc. Natl. Acad. Sci. 1993, 90, 11257-11261; Lobkovsky, E.; Billings, E. M.; Moews, P. C.; Rahil, J.; Pratt, R. F.; Knox, J. R. Biochemistry 1994, 33, 6762-6772; [ChemPort] [Medline] Usher, K. C.; Blaszczak, L. C.; Weston, G. S.; Shoichet, B. K.; Remington, S. J. Biochemistry 1998, 37, 16082-16092.[Full text - ACS] [ChemPort] [Medline] 9. Maveyraud, L.; Golemi, D.; Kotra, L. P.; Tranier, S.; Vakulenko, S.; Mobashery, S.; Samama, J. P. Struct. Fold. Des. 2000, 8, 1289; [ChemPort] [CrossRef] Maveyraud, L.; Golemi-Kotra, D.; Ishiwata, A.; Meroueh, O.; Mobashery, S.; Samama, J. P. J. Am. Chem. Soc. 2002, 124, 2461-2465.[Full text - ACS] [ChemPort] [Medline] 10. Leung, Y.-C.; Robinson, C. V.; Aplin, R. T.; Waley, S. G. Biochem. J. 1994, 299, 671-678; [ChemPort] [Medline] Brown, R. P.; Aplin, R. T.; Schofield, C. J. Biochemistry 1996, 35, 12421-12432.[Full text - ACS] [ChemPort] [Medline] 11. Fisher, J.; Belasco, J. G.; Khosla, S.; Knowles, J. R. Biochemistry 1980, 19, 2895-2901; [ChemPort] [Medline] Wilkinson, A.-S.; Bryant, P. K.; Meroueh, S. O.; Page, M. G.; Mobashery, S.; Wharton, C. W. Biochemistry 2003, 42, 1950-1957.[Full text - ACS] [ChemPort] [Medline] 12. Page. M. I.; Vilanova, B.; Layland, N. J. J. Am. Chem. Soc. 1995, 117, 12092-12095. 13. Christensen, H.; Martin, M. T.; Waley, S. G. Biochem. J. 1990, 266, 853-861. [ChemPort] [Medline] 14. Strynadka, N. C.; Adachi, H.; Jensen, S. E.; Johns, K.; Sielecki, A.; Betzel, C.; Sutoh, K.; James, M. N. Nature 1992, 359, 700-705; [ChemPort] [Medline] [CrossRef] Beadle, B. M.; Shoichet, B. K. Antimicrob. Agents Chemother. 2002, 46, 3978-3980. [ChemPort] [Medline] [CrossRef] 15. Matagne, A.; Frère, J.-M. Biochim. Biophys. Acta 1995, 1246, 109-127. [Medline] [CrossRef] 16. Minasov, G.; Wang, X.; Shoichet, B. K. J. Am. Chem. Soc. 2002, 124, 5333-5340.[Full text - ACS] [ChemPort] [Medline] 17. Page, M. I. Curr. Pharm. Des. 1999, 5, 895-913. [ChemPort] [Medline] 18. Damblon, C.; Zhao, G. H.; Jamin, M.; Ledent, P.; Dubus, A.; Vanhove, M.; Raquet, X.; Christiaens, L.; Frère, J.-M. Biochem. J. 1995, 309, 431-436; [ChemPort] [Medline] Xu, Y.; Soto, G.; Hirsch, K. R.; Pratt, R. F. Biochemistry 1996, 35, 3595-3603;[Full text - ACS] [ChemPort] [Medline] Murphy, B. P.; Pratt, R. F. Biochemistry 1991, 30, 3640-3649. 19. Dubus, A., Normark, S.; Kania, M.; Page, M. G. Biochemistry 1994, 33, 8577-8586; [ChemPort] [Medline] Dubus. A., Ledent, P., Lamotte-Brasseur, J., Frère, J.-M. Proteins 1996, 25, 473-485. [Medline] 20. Page, M. I. Acc. Chem. Res. 2004, 37, 297-303.[Full text - ACS] [ChemPort] [Medline] 21. Wood, J. M.; Page, M. I. Trends Heterocycl. Chem. 2002, 8, 19-34. [ChemPort] 22. King, J. F.; Rathore, R.; Lam, J. Y. L.; Guo, Z. R.; Klassen, D. F. J. Am. Chem. Soc. 1992, 114, 3028-3033. [ChemPort] 23. Baxter, N. J.; Rigoreau, L. J. M.; Laws, A. P.; Page, M. I. J. Am. Chem. Soc. 2000, 122, 3375-3385.[Full text - ACS] [ChemPort] 24. Baxter, N. J.; Laws, A. P.; Rigoreau, L.; Page, M. I. J. Chem. Soc., Perkin Trans 2 1996, 2245-2246. [ChemPort] [CrossRef] 25. Page, M. I.; Williams, A. In Organic and BioOrganic Mechanisms; Longman, 1997. 26. Pratt, R. F. Science 1989, 246, 917-919; [ChemPort] [Medline] Rahil, J.; Pratt, R. F. Biochem. J. 1991, 275, 793-795. [ChemPort] [Medline] 27. Llinás, A.; Ahmed, N.; Cordaro, M.; Laws, A. P.; Frère, J.-M.; Delmarcelle, M.; Silvaggi, N. R.; Kelly, J. A.; Page, M. I. Biochemistry 2005, 44, 7738-7746.[Full text - ACS] [ChemPort] 28. Hinchliffe, P. S.; Wood, J. M.; Davis, A. M.; Austin, R. P.; Page, M. I. Org. Biomol. Chem. 2003, 1, 67-80. [ChemPort] [Medline] [CrossRef] 29. Photaki, I. J. Am. Chem. Soc. 1963, 85, 1123-1126; [ChemPort] Samuel, D.; Silver, B. L. J. Chem. Soc. 1963, 85, 1197-1198. [ChemPort] [CrossRef] 30. Anderson, L.; Kelly, J. J. J. Am. Chem. Soc. 1959, 81, 2275-2276. [ChemPort] 31. Ako, H.; Foster, R. J.; Ryan, C. A. Biochemistry 1974, 13, 132-139; [ChemPort] [Medline] Weiner, H.; White, W. N.; Hoare, D. G.; Koshland Jr., D. E. J. Am. Chem. Soc. 1966, 88, 3851-3859. [Medline] 32. Galleni, M.; Lindberg, F.; Normark, S.; Cole, S.; Honore, N.; Joris, B.; Frère, J.-M. Biochem. J. 1988, 250, 753-760; [ChemPort] [Medline] Rahil, J.; Pratt, R. F. Biochemistry 1992, 31, 5869-5878. [ChemPort] [Medline] 33. Madonna, M. J., Zhu, Y. F.; Lampen, J. O. Nucleic Acids Res. 1987, 15, 1877; [ChemPort] [Medline] Patchornik, A.; Sokolovsky, M. J. Am. Chem. Soc. 1964, 86, 1860-1861; Ziegler, K. J. Biol. Chem. 1964, 239, 2713-2714; Creamer, L. K.; Matheson, A. R. N. Z. J. Dairy Sci. Technol. 1977, 12, 253-259 34. Cohen, S. A.; Pratt, R. F. Biochemistry 1980, 19, 3996-4003. [ChemPort] [Medline] 35. Macdonald, S. J. F.; Belton, D. J.; Buckley, D. M.; Spooner, J. E.; Anson, M. S.; Harrison, L. A.; Mills, K.; Upton, R. J.; Dowle, M. D.; Smith, R. A.; Molloy, C. R.; Risley, C. J. Med. Chem. 1998, 41, 3919-3922;[Full text - ACS] [ChemPort] [Medline] Macdonald, S. J. F., et al. Bioorg. Med. Chem. Lett. 2001, 11, 243-246; [Medline] [CrossRef] Macdonald, S. J. F., et al. Bioorg. Med. Chem. Lett. 2001, 11, 895-898. [Medline] [CrossRef] 36. Menger, F. M. Acc. Chem. Res. 1985, 18, 128-134; [ChemPort] Menger, F. M. Acc. Chem. Res. 1993, 26, 206-212; [ChemPort] Dafforn, A.; Koshland, D. E., Jr. Proc. Natl. Acad. Sci. 1971, 68, 2463-2467; [ChemPort] Kirby, A. J. Acc. Chem. Res. 1997, 30, 290-296;[Full text - ACS] [ChemPort] Kirby, A. J. Angew. Chem., Int. Ed. Engl. 1996, 35, 706-724. [CrossRef] 37. Page, M. I.; Laws, A. P.; Slater, M. J.; Stone, J. R. Pure Appl. Chem. 1995, 67, 711-717; [ChemPort] Laws, A. P.; Page, M. I.; Slater, M. J. Bioorg. Med. Chem. Lett. 1993, 3, 2317-2322. [ChemPort] [CrossRef] 38. Williams, A. Adv. Phys. Org. Chem. 1992, 27, 1-55. 39. Proctor, P.; Gensmantel, N. P.; Page, M. I. J. Chem. Soc., Perkin Trans. 2. 1982, 1185-1192; Page, M. I. Adv. Phys. Org. Chem. 1987, 23, 165-270. 40. Faist, V.; Drusch, S.; Kiesner, C.; Elmadfa, I.; Erbersdobler, H. F. Int. Dairy J. 2000, 10, 339-346. [ChemPort] [CrossRef] ', 'date_year' => '2005', 'status_changed_hour' => '18', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '21241' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1409831515', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Parkes', 'eprintid' => '21241', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Gareth M.B', 'creators_id' => 'g.m.b.parkes@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '21241', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Townend', 'eprintid' => '21241', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'James D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2014', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/21241/1/Hardingc4an00859f.pdf', 'status_changed_second' => '2', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Parameters affecting ion intensities in transmission-mode Direct Analysis in Real-Time mass spectrometry', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/02/12/41', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '53', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C4AN00859F', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '4', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '4176-4180', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2014', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Analyst', 'lastmod_second' => '8', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0003-2654', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '3', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 9, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '21241', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2014', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20140900', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '17', 'rev_number' => '8', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '12', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '22', 'abstract' => 'A survey of the effect of temperature, transmission module material and analysis time on ion intensities in transmission mode direct analysis in real time mass spectrometry is presented. Ion intensity profiles obtained for two related compounds are similar when analysed separately but are very different when analysed as a mixture.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '12', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/C4AN00859F', 'volume' => '139', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2014', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '8234' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1308050263', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Martina', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Faulkner', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Robert A.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Allen', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Kirsty E.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Voss', 'eprintid' => '8234', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Melanie L.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2010', 'fileinfo' => '', 'status_changed_second' => '52', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Head-To-Tail and Heteroleptic Pentanuclear Circular Helicates', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/82/34', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '19', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://www3.interscience.wiley.com/journal/123595685/abstract', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '14', 'publisher' => 'Wiley', 'pagerange' => '6655-6658', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2010', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Angewandte Chemie International Edition', 'lastmod_second' => '53', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1433-7851', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '52', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 9, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '8234', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2011', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '6', 'event_dates' => undef, 'fulltimestamp' => '20100900', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '37', 'rev_number' => '10', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '30', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '3', 'datestamp_day' => '3', 'abstract' => 'Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N-donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head-to-tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands).', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '30', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1002/anie.201003342', 'volume' => '49', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '4156' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Paul', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Rowena L.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward`', 'eprintid' => '4156', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '5', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '17', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Cadmium-containing pyridyl–thiazole complexes: crystal structures and solution behaviour of mononuclear, dinuclear double helicate and dinuclear triple helicate complexes', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/41/56', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '52', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/S0277-5387(02)01406-7', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '5', 'publisher' => 'Pergamon', 'pagerange' => '755-762', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Polyhedron', 'lastmod_second' => '17', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '02775387', 'datestamp_hour' => '12', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '17', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '4156', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '5', 'event_dates' => undef, 'fulltimestamp' => '20030300', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '5', 'rev_number' => '10', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '52', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'Reaction of Cd(ClO4)2 with the potentially tetra- (L1), penta- (L2) and hexadentate (L3) pyridine–thiazole-containing ligands gives [Cd2(L1)3(H2O)][ClO4]4 (a dinuclear triple helicate), mononuclear [Cd(L2)(ClO4)2], and [Cd2(L3)2(ClO4)(CH3CN)][ClO4]3 (a dinuclear double helicate), respectively. In [Cd2(L1)3(H2O)][ClO4]4 two of the ligands L1 partition into two bidentate pyridyl–thiazole domains whereas the remaining ligand partitions into a bidentate (pyridyl–thiazole) and monodentate (coordinating pyridyl unit with a pendant thiazole) unit; one Cd(II) centre is coordinated by three bidentate ligand fragments, whereas the other is coordinated by two bidentate and one monodentate ligand fragments as well as a water molecule. This low-symmetry arrangement is retained in solution. In [Cd(L2)(ClO4)2], L2 acts as a planar pentadentate equatorial ligand with perchlorate anions coordinated at the axial sites; the ligand has a shallow helical twist to minimise steric interactions between the terminal pyridyl H6 protons, which are directed towards each other. In [Cd2(L3)2(ClO4)(CH3CN)][ClO4]3, the potentially hexadentate ligand L3 is partitioned into terdentate (pyridyl–thiazole–pyridyl) and bidentate (pyridyl–thiazole) coordination domains with a non-coordinated terminal pyridyl unit; each Cd(II) centre is coordinated by one terdentate and one bidentate ligand fragment, with the sixth site being occupied by MeCN at one Cd(II) site and a perchlorate anion at the other. Again, the low symmetry coordination mode of the ligands is retained in solution although the two metal centres become equivalent.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '52', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1016/S0277-5387(02)01406-7', 'volume' => '22', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2003', 'status_changed_hour' => '12', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3486' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clayton', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Hayley J.', 'creators_id' => undef }, '7' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '7', 'creators_name_given' => 'Martina', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Irvine', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'J.P.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '3486', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '57', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Metal-specific allosteric activation and deactivation of a diamine', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/86', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '14', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b714256k', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '25', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '108', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '57', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1364-548X', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '57', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 1, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3486', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080100', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '1', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '14', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '25', 'datestamp_day' => '25', 'abstract' => 'The reaction of a potentially tetradentate bis(pyridyl–thiazole) ligand with acetone is allosterically activated upon complexation with Cd(II) but deactivated by reaction with Cu(I), demonstrating metal-specific allosteric controlled reactivity.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '14', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b714256k', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '13205' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1347352153', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '13205', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ahmed', 'eprintid' => '13205', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Amira', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Chrystyn', 'eprintid' => '13205', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Henry', 'creators_id' => 'h.chrystyn@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '4', 'editors_name_honourific' => undef, 'admin_note' => 'Emailed author for PP SJT 17/4/12', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '', 'status_changed_second' => '2', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Urinary pharmacokinetic methodology to determine the relative lung availability of inhaled beclometasone', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/32/05', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '30', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1111/j.1365-2125.2012.04210.x', 'succeeds' => undef, 'datestamp_month' => '4', 'commentary' => undef, 'lastmod_day' => '11', 'publisher' => 'Wiley', 'pagerange' => '456-464', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'British Journal of Clinical Pharmacology', 'lastmod_second' => '18', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1365-2125', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '2', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 9, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '13205', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2012', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20120900', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '8', 'number' => '3', 'rev_number' => '8', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'RS', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '33', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '17', 'datestamp_day' => '17', 'abstract' => 'Background: Urinary pharmacokinetic methods have been identified to determine the relative lung and systemic bioavailability after an inhalation. We have extended this methodology to inhaled beclometasone dipropionate (BDP). Methods: Ethical approval was obtained and all subjects gave consent. Twelve healthy- volunteers received randomised doses, separated by >7 days, of 2000µg BDP solution with (OralC) and without (Oral) 5g oral charcoal, ten 100µg inhalations from a Qvar® Easibreathe metered dose inhaler (pMDI) with (QvarC) and without (Qvar) oral charcoal and eight 250µg inhalations from a Clenil® pMDI (Clenil). Subjects provided urine samples at 0, 0.5, 1, 2, 3, 5, 8, 12, and 24 hours post study dose.Urinary concentrations of BDP and its metabolites, beclometasone -17- monopropionate (BMP) and beclometasone (BOH) were measured. Results: No BDP, BMP, or BOH was detected in any samples post OralC dosing. Post oral dosing no BDP was detected in all urine samples and no BMP or BOH was excreted in the first 30 minutes. Significantly more (p < 0.001) BDP, BMP and BOH was excreted in the first 30 minutes and cumulative 24 urinary excretions post Qvar and Clenil compared to Oral. Using 30 minute urinary excretion the mean ratio (90% confidence interval) for Qvar compared to Clenil was 231.4 (209.6, 255.7). Conclusions: The urinary pharmacokinetic methodology to determine the relative lung and systemic bioavailability post inhalation, using 30 minute and pooled 24 hour post inhalation samples, applies to BDP. The ratio between Qvar and Clenil is consistent with related clinical and gamma scintigraphy lung deposition studies. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '33', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1111/j.1365-2125.2012.04210.x', 'volume' => '74', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2012', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3460' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '3460', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Westcott', 'eprintid' => '3460', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Aleema', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '3460', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3460', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '45', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Flattened trigonal bipyramidal coordination assembly with trans geometry', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/60', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '37', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b716733b', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '276-278', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'CrystEngComm', 'lastmod_second' => '56', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1466-8033', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '45', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3460', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080300', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '3', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '2', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'Pd(O2CCH3)2 and ligand L1 = N,N,N-tris(6-methyl-2-pyridyl)benzene-1,3,5-tricarboxamide self-assemble into the trigonal bipyramidal complex [Pd3(L1)2(O2CCH3)6] in solution and the solid state, the latter giving a robust 3-D network structure.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '2', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b716733b', 'volume' => '10', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '11602' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1318498824', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Halcrow', 'eprintid' => '11602', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Malcolm A', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '11602', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Little', 'eprintid' => '11602', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Marc A', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '11602', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '10', 'editors_name_honourific' => undef, 'admin_note' => 'Emailed permission for PP SJT 13/10/11', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2011', 'fileinfo' => '', 'status_changed_second' => '12', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Ag(I) organometallic coordination polymers and capsule with tris-allyl cyclotriveratrylene derivatives', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/16/02', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '41', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 18, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/ 10.1021/ic101211n', 'succeeds' => undef, 'datestamp_month' => '10', 'commentary' => undef, 'lastmod_day' => '13', 'publisher' => 'American Chemical Society', 'pagerange' => '9486-9496', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2011', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganic Chemistry', 'lastmod_second' => '12', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '00201669', 'datestamp_hour' => '9', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '12', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '11602', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2011', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20101018', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => '20', 'rev_number' => '8', 'edit_lock_user' => '6', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '41', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including ?2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '41', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => ' 10.1021/ic101211n', 'volume' => '49', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '9', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '8224' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1280415552', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Carruthers', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Christopher', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Brotin', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Thierry', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rizkallah', 'eprintid' => '8224', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Pierre J.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2010', 'fileinfo' => '', 'status_changed_second' => '37', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Tripodal 4-Pyridyl-Derived Host Ligands and Their Metallo-Supramolecular Chemistry: Stella Octangula and Bowl-Shaped Assemblies', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/82/24', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '1', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ic901972h', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '29', 'publisher' => 'American Chemical Society', 'pagerange' => '675-685', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2010', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganic Chemistry', 'lastmod_second' => '37', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '00201669', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '37', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 1, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '8224', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20100100', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '15', 'number' => '2', 'rev_number' => '7', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '1', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '29', 'datestamp_day' => '29', 'abstract' => 'The synthesis of five new cyclotriveratrylene derivatives with 4-pyridyl side arms is reported, along with the crystal structures of three of these. Three ligands with extended 4-pyridylphenyl side arms and a ligand derived from cyclotriphenolene have been shown to form [Pd6L8]12+ stella octangula assemblies using diffusion-ordered spectroscopy NMR and electrospray MS techniques. This confirms the generality of the stella octagula assembly, providing that the ligand arms show a degree of rigidity. The more flexible ether-linked ligand tris(4-pyridylmethyl)cyclotriguaiacylene forms a smaller [Pd3L4]6+ bowl-shaped assembly in the solid state and in solution. The previously reported ligand tris(4-pyridylmethylamino)cyclotriguaiacylene forms a similar assembly in solution. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '1', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1021/ic901972h', 'volume' => '49', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '511' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laws', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Andrew P.', 'creators_id' => 'a.p.laws@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ahmed', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Naveed', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hemming', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Karl', 'creators_id' => 'k.hemming@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Tsang', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Wing Y.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Page', 'eprintid' => '511', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael I.', 'creators_id' => 'm.i.page@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '55', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Acylation versus sulfonylation in the inhibition of elastase by 3-oxo-beta-sultams ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/11', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '20', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2005/127/i25/abs/ja050787z.html', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'The American Chemical Society', 'pagerange' => '8946-8947', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the American Chemical Society', 'lastmod_second' => '54', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1520-5126', 'datestamp_hour' => '9', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '55', 'note' => 'Copyright © 2005 American Chemical Society ', 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '511', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => '25', 'rev_number' => '19', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '37', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '8', 'datestamp_day' => '8', 'abstract' => '-Sultams are the sulfonyl analogues of -lactams, and 3-oxo- -sultams are both -lactams and -sultams and, therefore, susceptible to nucleophilic attack at either the acyl or the sulfonyl center. They are novel inactivators of serine enzymes. The second-order rate constant for the inactivation of elastase at pH 6 by N-benzyl-4,4-dimethyl-3-oxo- -sultam is 768 M-1 s-1, which is 103-fold greater than However, in contrast to N-acyl -sultams, which sulfonylate the active site serine residue to form a sulfonate ester, 3 acylation followed by slow deacylation to regenerate the active enzyme.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '37', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ja050787z', 'volume' => '127', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '(1) Baxter, N. J.; Rigoreau, L. J. M.; Laws, A. P.; Page, M. I. J. Am. Chem. Soc. 2000, 112, 3375-3385; J. Chem. Soc., Perkin Trans. 2 1996, 2245- 2246. (2) Hinchliffe, P. S.; Wood, J. M.; Davis, A. M.; Austin, R. P.; Beckett, R. P.; Page, M. I. Org. Biomol. Chem. 2003, 1, 67-80. (3) Page, M. I. Enzyme Inhibition. In ComprehensiVe Medicinal Chemistry; Sammes, P. G., Ed.; Pergamon: Oxford, 1990; Vol. 2, pp 61-87. (4) Metz, W. A.; Peet, N. P. Prog. Inflammation Res. 1999, 9, 853-868. (5) Bode, W.; Meyer, E., Jr.; Powers, J. C. Biochemistry 1989, 28, 1951- 1963. (6) Macdonald, S. J. F. et al. Bioorg. Med. Chem. Lett. 2001, 11, 895-898. (7) Page M. I., Ed. The Chemistry of â-Lactams; Blackie: Glasgow, 1992. (8) (a) Chabin, R.; Green, B. G.; Gale, P.; Maycock, A. L.; Weston, H.; Dorn, C. P.; Finke, P. E.; Hagmann, W. K.; Hale, J. J.; MacCoss, M.; Shah, S. K.; Underwood, D.; Doherty, J. B.; Knight, W. B. Biochemistry 1993, 32, 8970-8980. (b) Beauve, C.; Bouchet, M.; Touillaux, R.; Fastrez, J.; Marchand-Brynaert, J. Tetrahedron 1999, 55, 13301-13320. (9) Wood, J. M.; Page, M. I. Trends Heterocycl. Chem. 2002, 8, 19-34. (10) Page, M. I. Acc. Chem. Res. 2004, 37, 297-303. (11) Macdonald, S. J. F. et al. Bioorg. Med. Chem. Lett. 2001, 11, 243-246. (12) Sykes, N. O.; Macdonald, S. J. F.; Page, M. I. J. Med. Chem. 2002, 45, 2850-2856. (13) Ahmed, N.; Tsang, W. Y.; Page, M. I. Org. Lett. 2004, 6, 201-203. (14) (a) Eriksson, S. O.; Jakobsson M. Acta Pharm. Suec. 1973, 10, 63-74. (b) Matsui, S.; Aida H. J. Chem. Soc., Perkin Trans. 2 1978, 1277- 1280. (15) Wilmouth, R. C.; Westwood, N. J.; Anderson, K.; Brownlee, W.; Claridge, T. D. W.; Clifton, I. J.; Pritchard, G. J.; Aplin, R. T.; Schofield, C. J. Biochemistry 1998, 37, 17506-17513. (16) Firestone, R. A.; Barker, P. L.; Pisano, J. M.; Ashe, B. M.; Dahlgren, M. E. Tetrahedron 1990, 46, 2255-2262. JA050787Z', 'date_year' => '2005', 'status_changed_hour' => '9', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '21239' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1410855626', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '21239', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '21239', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '21239', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Oliver R.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Miller', 'eprintid' => '21239', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John W.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => 'Open access journal, published version allowed per sherpa', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2014', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/21239/1/lh5644_final.pdf', 'status_changed_second' => '1', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Tricarbonylchlorido(6'7'-dihydro-5’H-spiro[cyclopentane-1,6'-dipyrido-[3,2-d:2',3'-f][1,3]diazepine]-?2N1,N11)-rhenium(I)', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/02/12/39', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '21', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1107/S1600536813023076', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '16', 'publisher' => 'International Union of Crystallography ', 'pagerange' => 'm526', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2014', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Acta Crystallographica Section E', 'lastmod_second' => '12', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1600-5368', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '2', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '21239', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2014', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20131000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '8', 'number' => '10', 'rev_number' => '8', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '58', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '17', 'datestamp_day' => '17', 'abstract' => 'In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '58', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1107/S1600536813023076', 'volume' => '69', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2013', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '11603' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1318499097', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '11603', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Henkelis', 'eprintid' => '11603', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'James J', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '11603', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '11603', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '10', 'editors_name_honourific' => undef, 'admin_note' => 'Emailed author for PP SJT 13/10/11', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2011', 'fileinfo' => '', 'status_changed_second' => '8', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'M3L2 metallo-cryptophanes: [2]catenane and simple cages', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/16/03', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '20', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C1CC10806A ', 'succeeds' => undef, 'datestamp_month' => '10', 'commentary' => undef, 'lastmod_day' => '13', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '6560-6562', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2011', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '8', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '13597345', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '8', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 11, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '11603', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2011', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20111100', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '23', 'rev_number' => '6', 'edit_lock_user' => '6', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '20', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'Crystalline M3L2 complexes with either single cage or triply interlocking [2]catenane chiral structures are formed the self-assembly of host-like ligands with transition metals. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '20', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/C1CC10806A ', 'volume' => '47', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2011', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '7770' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Martina', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bullock', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Sam', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Midgley', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Gary', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bain', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '7770', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '5', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2010', 'fileinfo' => '', 'status_changed_second' => '58', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Controlling the formation of metallosupramolecular assemblies by metal ionic radii', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/77/70', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '20', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b920840b', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '27', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '3496-3498', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2010', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '58', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '58', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 6, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '7770', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '5', 'event_dates' => undef, 'fulltimestamp' => '20100600', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '20', 'rev_number' => '9', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '20', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '27', 'datestamp_day' => '27', 'abstract' => 'The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the size of the metal ion', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '20', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b920840b', 'volume' => '46', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '941' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'William', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harrington', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Ross W.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '941', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '6', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '33', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Synthesis and structures of cadmium(II) complexes of a series of multinucleating N/S donor ligands', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/41', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '32', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/j.poly.2007.01.012', 'succeeds' => undef, 'datestamp_month' => '6', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Pergamon', 'pagerange' => '2777-2785', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Polyhedron', 'lastmod_second' => '2', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '02775387', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '33', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '941', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '12', 'rev_number' => '14', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '42', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '30', 'datestamp_day' => '30', 'abstract' => 'The coordination chemistry of a series of bis-bidentate ligands with cadmium(II) ions has been investigated. The ligands, containing two N,S-donor chelating (pyrazolyl/thioether) fragments, have afforded complexes of a variety of structural types (dinuclear M2L2 ‘mesocate’ complexes, a one-dimensional chain coordination polymer and a simple mononuclear complex) according to whether the bis-bidentate ligands act as bridges spanning two metal ions, or a tetradentate chelate to a single metal ion. The p-phenylene and m-biphenyl spaced ligands L1 and L3 form dinuclear M2L2 complexes where the ligands are arranged in a ‘side-by-side’ fashion. In contrast the m-phenylene spaced ligand L2 forms a one-dimensional coordination polymer where the ligands adopt a highly folded conformation. The 1,8-naphthalene spaced ligand L4 adopts a tetradendate chelating mode and affords a simple mononuclear complex', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '42', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1016/j.poly.2007.01.012', 'volume' => '26', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '13144' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1332416943', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fennessy', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Rebecca V.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Oliver R.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fletcher', 'eprintid' => '13144', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Nicholas C.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '', 'status_changed_second' => '29', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Diastereoselective assembly of pentanuclear circular helicates', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/31/44', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '49', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C1DT11414J', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '22', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '12381-12387', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '17', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1477-9226', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '29', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '13144', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2012', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20111000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '45', 'rev_number' => '8', 'edit_lock_user' => '116', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '48', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '22', 'abstract' => 'Reaction of a ligand which contains two N-donor and O-donor tridentate domains separated by a 1,3-phenylene spacer unit with Zn2+ ions results in a pentanuclear circular helicate [Zn5(L)5]10+ and this structure persists in both the solid and solution state. The formation of this high nuclearity species is governed by unfavourable steric interactions between the phenyl units which destabilize the simple linear helicate. Incorporation of enantiopure units within the ligand strand controls the diastereoselectivity with up to 80% d.e.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '48', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/C1DT11414J', 'volume' => '40', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2011', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '2595' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Paul', 'eprintid' => '2595', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Rowena L.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '2595', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '2595', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '2595', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '2595', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '11', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '43', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Pyridyl-thiazole multidentate ligands: metal-specific recognition of a combination of ligands from a mixture', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/25/95', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '55', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b104977c', 'succeeds' => undef, 'datestamp_month' => '11', 'commentary' => undef, 'lastmod_day' => '11', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '3039-3044', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Journal of the Chemical Society Dalton Transactions', 'lastmod_second' => '43', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1472-7773', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '43', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '2595', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '11', 'event_dates' => undef, 'fulltimestamp' => '20011000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '11', 'number' => '20', 'rev_number' => '9', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'TP', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '55', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '11', 'datestamp_day' => '11', 'abstract' => 'Comparison of the crystal structures of the dinuclear double helicates [M2(L1)2][ClO4]4 (M = Ni, Zn; L1 is a potentially hexadentate ligand containing a py–th–py–py–th–py sequence, where ‘py’ denotes pyridyl and ‘th’ denotes thiazolyl) illustrates how L1 can show two different coordination modes: in [Zn2(L1)2][ClO4]4 the ligands L1 are bisbidentate chelates (via the terminal py–th fragments, with the central bipyridyl unit not coordinated) such that the metal ions are four-coordinate, whereas in [Ni2(L1)2][ClO4]4 the ligand coordinates in a more usual bis-terdentate manner such that the metal ions are six-coordinate. Reaction of Ni(??), Cu(??) or Zn(??) salts with a 1 : 1 mixture of the potentially hexadentate ligands L1 and L2 (where L2 contains a phen–th–th–phen sequence, ‘phen’ denoting a 1,10- phenanthroline unit) afforded in each case a mixture of helical complexes [M2(L1)2]4, [M2(L1)(L2)]4 and [M2(L2)2]4 in different proportions according to the preferences of the different metal ions for different coordination numbers, and the actual denticity of the ligand. For example the mixed-ligand complex [M2(L1)(L2)]4 was formed to the same extent (ca. 50%) for M = Ni and M = Cu, but hardly at all for M = Zn, indicating that self–self ligand recognition operates during assembly of L1 and L2 with Zn(??) such that the homoleptic complexes [Zn2(L1)2]4 and [Zn2(L2)2]4 are favoured more than simple statistical considerations would suggest.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '5', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '55', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi: 10.1039/b104977c', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2001', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '8220' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1280414615', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jones', 'eprintid' => '8220', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Jennifer E.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Andrews', 'eprintid' => '8220', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Michael', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '8220', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '8220', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2010', 'fileinfo' => '', 'status_changed_second' => '55', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Luminescent probes based on water-soluble, dual-emissive lanthanide complexes: metal ion-induced modulation of near-IR emission', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/82/20', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '46', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/c0cc00210k', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '29', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2010', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '55', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '55', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 6, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '8220', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20100600', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '14', 'number' => undef, 'rev_number' => '7', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '46', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '29', 'datestamp_day' => '29', 'abstract' => 'Responsive lanthanide complexes demonstrate differentiated modulated luminescence output upon exposure to metal di-cations in aqueous solution.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '46', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/c0cc00210k', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '5475' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Warren', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'John E.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ronson', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Tanya K.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rizkallah', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Pierre J.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '5475', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '51', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Stellated polyhedral assembly of a topologically complicated Pd4L4 ‘Solomon cube’', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/54/75', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '17', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1038/nchem.213', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Nature', 'pagerange' => '212-216', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Nature Chemistry', 'lastmod_second' => '51', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '17554330', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '51', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 6, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '5475', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '8', 'event_dates' => undef, 'fulltimestamp' => '20090600', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '15', 'number' => '3', 'rev_number' => '8', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '17', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '26', 'datestamp_day' => '26', 'abstract' => 'Metallosupramolecular chemistry relies on self-assembly processes in which complicated species form through labile dative-covalent interactions. Two remarkable areas of this chemistry are the synthesis of topologically complicated threaded assemblies and of three-dimensional (3D) polyhedral assemblies. Very few polyhedral 3D metallosupramolecular assemblies show threaded motifs within them. Here we report an example of a new type of threaded 3D metallosupramolecular assembly built from four organic ligands and four palladium ions, a Pd4L4 so-called 'Solomon's cube' in which interweaving and twisting of the ligands form both Solomon's links and figure-of-eight ring motifs. In the solid state, six of these Pd4L4 tetramers assemble into a hollow spheroid that closely resembles a stellated truncated hexahedron.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '17', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1038/nchem.213', 'volume' => '1', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2009', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1207' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Martina', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Moon', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Ryan', 'creators_id' => 'r.moon@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '1207', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => undef, 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '15', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Allosteric-Controlled Metal Specificity of a Ditopic Ligand', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/12/07', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '13', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/anie.200502571', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '20', 'publisher' => 'Wiley', 'pagerange' => '6909-6912', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Angewandte Chemie International Edition', 'lastmod_second' => '52', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1433-7851', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '15', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1207', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20050000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '42', 'rev_number' => '13', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '54', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '24', 'datestamp_day' => '24', 'abstract' => undef, 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '54', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/anie.200502571', 'volume' => '44', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2005', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '968' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '968', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '968', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '968', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '968', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '968', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '4', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Ligand Reprogramming in Dinuclear Helicate Complexes: A Consequence of Allosteric or Electrostatic Effects?', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/68', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '44', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/chem.200700261', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Wiley - VCH Verlag GmbH & Co. KGaA', 'pagerange' => '5256-5271', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemistry - A European Journal', 'lastmod_second' => '7', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '09476539', 'datestamp_hour' => '8', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '4', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '968', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '18', 'rev_number' => '13', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '17', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '4', 'datestamp_day' => '4', 'abstract' => 'The ditopic ligand 6,6-bis(4-methylthiazol-2-yl)-3,3-([18]crown-6)-2,2-bipyridine (L1) contains both a potentially tetradentate pyridyl-thiazole (py-tz) N-donor chain and an additional external crown ether binding site which spans the central 2,2-bipyridine unit. In polar solvents (MeCN, MeNO2) this ligand forms complexes with ZnII, CdII, HgII and CuI ions via coordination of the N donors to the metal ion. Reaction with both HgII and CuI ions results in the self-assembly of dinuclear double-stranded helicate complexes. The ligands are partitioned by rotation about the central pypy bond, such that each can coordinate to both metals as a bis-bidentate donor ligand. With ZnII ions a single-stranded mononuclear species is formed in which one ligand coordinates the metal ion in a planar tetradentate fashion. Reaction with CdII ions gives rise to an equilibrium between both the dinuclear double-stranded helicate and the mononuclear species. These complexes can further coordinate s-block metal cations via the remote crown ether O-donor domains; a consequence of which are some remarkable changes in the binding modes of the N-donor domains. Reaction of the HgII- or CdII-containing helicate with either Ba2+ or Sr2+ ions effectively reprogrammes the ligand to form only the single-stranded heterobinuclear complexes [MM(L1)]4+ (M=HgII, CdII; M=Ba2+, Sr2+), where the transition and s-block cations reside in the N- and O-donor sites, respectively. In contrast, the same ions have only a minor structural impact on the ZnII species, which already exists as a single-stranded mononuclear complex. Similar reactions with the CdII system result in a shift in equilibrium towards the single-stranded species, the extent of which depends on the size and charge of the s-block cation in question. Reaction of the dicopper(I) double-stranded helicate with Ba2+ shows that the dinuclear structure still remains intact but the pitch length is significantly increased.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '17', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/chem.200700261', 'volume' => '13', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '8', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '951' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Moon', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Ryan', 'creators_id' => 'r.moon@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '951', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'T.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '6', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '51', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Electrostatic control of the formation of heteroleptic transition metal helicates', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/09/51', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '36', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b702608k', 'succeeds' => undef, 'datestamp_month' => '6', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '1525-1529', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'New Journal of Chemistry', 'lastmod_second' => '46', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '11440546', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '51', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '951', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20070000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '8', 'rev_number' => '13', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '58', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '30', 'datestamp_day' => '30', 'abstract' => 'The synthesis of the potentially hexadentate ditopic ligand L1, which contains both N-donor and crown ether binding units, is described. Reaction of L1 with Zn(II) results in the formation of a dinuclear double helicate ([Zn2(L1)2](ClO4)4), which has been structurally characterized. In the solid state, each ligand splits into two tridentate binding domains with two Zn(II) ions coordinated by two bridging ligands in a double helicate arrangement. This complex can further react with s-block metal ions via the crown ether unit resulting in the structurally characterized zinc-containing helicate [Zn2(L1)2Ba2](ClO4)8. Ligand recognition studies of this helicate with a ligand that does not contain the crown ether unit but does contain the same N-donor array (L2) demonstrates, via both 1H NMR and ESI-MS studies, that a ligand recognition process does occur and the major species observed are the homoleptic species ([Zn2(L1)2](ClO4)4 and [Zn2(L2)2](ClO4)4). Addition of barium ions to the mixture increases the amount of the heteroleptic species ([Zn2(L1)(L2)](ClO4)4) present, resulting in an equal amount of homoleptic and heteroleptic species. This change in ligand recognition properties is attributed to electrostatic effects', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '58', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b702608k', 'volume' => '31', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2007', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '261' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1284028728', 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'McLay', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'N.', 'creators_id' => 'n.mclay@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'T.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bokolinis', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'G.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '261', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '1', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2007', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/261/1/Rice_This_facile.pdf', 'status_changed_second' => '19', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/02/61', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'restricted', 'lastmod_minute' => '39', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b600597g', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '9', 'publisher' => undef, 'pagerange' => '1980-1982', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '16', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1364-548X', 'datestamp_hour' => undef, 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => undef, 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '261', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20060000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => undef, 'rev_number' => '11', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '31', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '13', 'abstract' => 'The ligand L1 forms a dinuclear double helicate with Cu+ but upon addition of Ba2+ to the system a side-by-side species is formed both in solution and in the solid state; in the presence of Na+ both the helicate and the side-by-side species are formed in roughly equal amounts in solution.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '12', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => undef, 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/b600597g', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => '1 J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995; J. W. Steed and J. L. Atwood, Supramolecular Chemistry, John Wiley and Sons, Chichester, 2000; M. J. Hannon and L. J. Childs, Supramol. Chem., 2004, 16, 7; M. Albrecht, Chem. Rev., 2001, 101, 3547; M. Albrecht, Chem. Soc. Rev., 1998, 27, 281; C. Piguet, G. Bernardinelli and G. Hopfgartner, Chem. Rev., 1997, 97, 2005; E. C. Constable, in Comprehensive Supramolecular Chemistry, vol. 9; Polynuclear Transition Metal Helicates, ed J.-P. Sauvage, Elsevier, Oxford, 1996, pp. 213. 2 C. J. Baylies, L. P. Harding, J. C. Jeffery, T. Riis-Johannessen and C. R. Rice, Angew. Chem., Int. Ed., 2004, 43, 4515. 3 C. J. Baylies, T. Riis-Johannessen, L. P. Harding, J. C. Jeffery, R. Moon, C. R. Rice and M. Whitehead, Angew. Chem., Int. Ed., 2005, 44, 6909. 4 C. J. Baylies, J. C. Jeffery, T. A. Miller, T. Riis-Johannessen and C. R. Rice, Chem. Commun., 2005, 4158. 5 The absorbance occurs ,350 nm, well within the ligand absorption region. Addition of either Na+ or Ba2+ metal ions to 1 results in a decrease in the absorption intensity in this region with the effect greatest for Ba2+. The dark red colour observed is presumably due to MLCT to the p* orbital of the planar bipyridine, which is usual for a Cu(I) system coordinated by bipyridine ligand. Upon reprogramming of the ligand strand the torsion angle of the bipyridine unit increases to 82u; with the bipyridine unit no longer planar and acting as a mono-dentate ligand the MLCT is quenched. 1982 | Chem. Commun., 2006, 1980–1982 This journal is The Royal Society of Chemistry 2006', 'date_year' => '2006', 'status_changed_hour' => '18', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '15205' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1349876243', 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Craig R.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hallett', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Andrew J. ', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Piela', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Sean A.F.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bullock', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Sam ', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Higginson', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Joshua J. ', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '15205', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Simon J.A. ', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '10', 'editors_name_honourific' => undef, 'admin_note' => 'Emailed author for PP SJT 9/10/12', 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/15205/1/HardingLPH_Dalton_2_Repository.pdf', 'status_changed_second' => '6', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/52/05', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '38', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/C2DT31476B', 'succeeds' => undef, 'datestamp_month' => '10', 'commentary' => undef, 'lastmod_day' => '27', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => undef, 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '4', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '6', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '15205', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2013', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '9', 'event_dates' => undef, 'fulltimestamp' => '20121000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '0', 'number' => undef, 'rev_number' => '15', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '18', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '9', 'datestamp_day' => '9', 'abstract' => 'A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’- bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '18', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1039/C2DT31476B', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2012', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1208' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1208', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1208', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1208', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '1208', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Robson', 'eprintid' => '1208', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Alex P.H.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => undef, 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '28', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Solution and solid-state complexes of the potentially tetradentate pyridyl-thiazole ligand 6,6?-bis(4-methylthiazol-2-yl)-2,2?-bipyridine with Co, Ni, Cu, Cd, Hg, Cu and Ag', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/12/08', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '15', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/j.ica.2005.03.002', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '20', 'publisher' => 'Elsevier', 'pagerange' => '2781-2798', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganica Chimica Acta', 'lastmod_second' => '59', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0020-1693', 'datestamp_hour' => '9', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '28', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 6, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1208', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20050600', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '9', 'rev_number' => '12', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '3', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '24', 'datestamp_day' => '24', 'abstract' => 'Reaction of the potentially tetradentate N-donor ligand 6,6?-bis(4-methylthiazol-2-yl)-2,2?-bipyridine (L1) with the transition metal dications CoII, NiII, CuII, CdII and HgII results in the formation of mononuclear [M(L1)]2+ complexes, in which a planar ligand coordinates to the metals via all four N-donors. In contrast, reaction of L1 with CuI and AgI monocations, affords dinuclear double stranded helicate species [M2(L1)2]2+ (where M = CuI or AgI), in which partitioning of the ligand into two bis-bidentate pyridyl-thiazole chelating units allows each ligand to bridge both metal centres. X-Ray crystallography, electrospray mass spectroscopy and NMR spectroscopy reveal that the complexes [Mn(L1)m]z+ (where n = 1, m = 1 and z = 2, when M = CoII, NiII, CuII, CdII and HgII; n = 2, m = 2 and z = 2, when M = CuI), retain their solid-state structures in solution. Conversely, whilst 1H NMR studies suggest that combination of equimolar amounts of Ag(X)(where ) and L1 (in either nitromethane or acetonitrile) results in the formation of a helicate in solution, in the solid-state, an anion-templating effect gives rise to either mononuclear or dinuclear helicate structures [Agn(L1)n][X]n (where n = 2 when X = OTf?; n = 1 when ). ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '116', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '3', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1016/j.ica.2005.03.002', 'volume' => '358', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2005', 'status_changed_hour' => '9', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '21240' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1406025473', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '21240', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '21240', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Clegg', 'eprintid' => '21240', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Oliver R.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Miller', 'eprintid' => '21240', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John W.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2014', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/21240/1/Hardinglh5645.pdf', 'status_changed_second' => '42', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Tricarbonylchlorido(6’,7’-dihydro-5’H-spiro[cyclohexane-1,6’-dipyrido[3,2-d :2’,3’-f][1,3]diazepine]-?2N1,N11)rhenium(I)', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/02/12/40', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '58', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1107/S1600536813024288', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '22', 'publisher' => 'International Union of Crystallography ', 'pagerange' => 'm527', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2014', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Acta Crystallographica Section E', 'lastmod_second' => '42', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1600-5368', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '42', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 10, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '21240', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2014', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20131000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => undef, 'rev_number' => '9', 'edit_lock_user' => '6', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '58', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '22', 'datestamp_day' => '22', 'abstract' => 'In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100). ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '58', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1107/S1600536813024288', 'volume' => '69', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2013', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1450' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Zeng', 'eprintid' => '1450', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Zuotao', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1450', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '1450', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1450', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1450', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Thomas', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '25', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Anion control of the formation of geometric isomers in a triple helical array ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/14/50', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '41', 'refereed' => 'FALSE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/B407487B', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '2396-2397', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '28', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '11', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '25', 'note' => 'Electronic supplementary information (ESI) available: Structure refinement. See http://www.rsc.org/suppdata/dt/b4/b407487b/', 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1450', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20040000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '16', 'rev_number' => '14', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '9', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '11', 'datestamp_day' => '11', 'abstract' => 'The amide-substituted unsymmetrical ligand L1 upon coordination to Co2+ forms the dinuclear triple helicate [Co2(L1)3]4+ which exists as both possible C1 and C3 symmetric geometric isomers in solution, however, upon addition of nitrate ions, the formation of an anion binding cavity is favoured and hence the sole product is the C3 symmetric isomer in which all three amide substituents are hydrogen bonded to the nitrate anion. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '9', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/B407487B', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2004', 'status_changed_hour' => '11', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '15208' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1360835364', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Barnett', 'eprintid' => '15208', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Sarah A. ', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Henkelis', 'eprintid' => '15208', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'James J.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '15208', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J. ', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '15208', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '10', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2012', 'fileinfo' => '/style/images/fileicons/application_pdf.png;/15208/1/hardingic300940k.pdf', 'status_changed_second' => '31', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Coordination polymers utilizing N-oxide functionalised host ligands', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/01/52/08', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'public', 'lastmod_minute' => '50', 'refereed' => 'TRUE', 'contact_email' => 'l.p.harding@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1021/ic300940k', 'succeeds' => undef, 'datestamp_month' => '10', 'commentary' => undef, 'lastmod_day' => '14', 'publisher' => 'American Chemical Society', 'pagerange' => '10657-10674', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2012', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganic Chemistry', 'lastmod_second' => '23', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0020-1669', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '31', 'note' => 'Reprinted with permission from Inorg. Chem., Article ASAP DOI: 10.1021/ic300940k Publication Date (Web): September 27, 2012 Copyright © 2012 American Chemical Society ', 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 9, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '15208', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2013', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20120900', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => '20', 'rev_number' => '9', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '38', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '9', 'datestamp_day' => '9', 'abstract' => 'Pyridyl functionalized host molecules are oxidized to their N-oxide analogues and form a series of coordination polymers and discrete complexes with transition metal cations. Complex {[Ag3(NMP)6(L1)2]·3(ClO4)}? where L1 = tris(isonicotinoyl-N-oxide)cyclotriguaiacylene, NMP = N-methylpyrrolidone, is a three-dimensional (3-D) 3,6-connected coordination polymer of pyrite-like (pyr) topology and features ligand unsupported argentophilic interactions, while two-dimensional (2-D) 3,6-connected coordination polymers with the rarely reported kagome dual (kgd) topology are found for [M(L1)2]2+ where M = Zn, Cd, Cu. Ligand L2 = tris(nicotinoyl-N-oxide)cyclotriguaiacylene forms a 2-D coordination polymer with 44 (sql) grid topology in complexes {[M(L2)2(DMF)2]·2ClO4·8(DMF)}? M = Cd or Cu, DMF = N,N?-dimethylformamide, and a double-linked chain structure in {[Co(L2)2(DMF)2]·2NO3·4(DMF)·H2O}?, and both types of structure feature hand-shake self-inclusion motifs either within or between the polymers. 2-D coordination networks with 63 (hcb) topologies are found in complexes {[M(L3)(NO3)2]·2(DMF)}? (M = Cd, Zn) and {[Cu5(L3)2Cl10(NMP)4]}? where L3 = tris(2-pyridylmethyl)cyclotriguaiacylene, while [Ag2(L3)2(NMP)4]·2(BF4)·2(NMP) has a discrete dimeric structure which again shows hand-shake host–guest interactions supported by ?–? stacking. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '939', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '38', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ic300940k', 'volume' => '51', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2012', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '4159' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Lynam', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Jason M.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Paul', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Rowena L.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '4159', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '5', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => undef, 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '31', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Structures and anion-binding properties of M4L6 tetrahedral cage complexes with large central cavities', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/41/59', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '10', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/B409809A', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '5', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '3453-3458', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '31', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '13', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '31', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '4159', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '5', 'event_dates' => undef, 'fulltimestamp' => '20040000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '13', 'number' => '21', 'rev_number' => '10', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '10', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'Reaction of the bis-bidentate bridging ligand L3, in which two bidentate chelating 3(2-pyridyl)pyrazole units are separated by a 3,3-biphenyl spacer, with Co(II) salts affords tetranuclear cage complexes of composition [Co4(L3)6]X8(X =[BF4]–, [ClO4]–, [PF6]– or I–) in which four 6-coordinate Co(II) ions in an approximately tetrahedral array are connected by six bis-bidentate bridging ligands, one spanning each of the six edges of the Co4 tetrahedron. In every case, X-ray crystallography reveals that the apical Co(II) ion has a fac tris-chelate geometry, whereas the other three Co(II) ions have mer tris-chelate geometries, resulting in (non-crystallographic)C3 symmetry for the cages; that this structure is retained in solution is confirmed by 1H NMR spectroscopy of the paramagnetic cages. In every case one of the anions is located inside the central cavity of the cage, with the remaining seven outside. We found no clear evidence for an anion-based templating effect. The cage superstructure is sufficiently large to leave gaps in the centres of the faces through which the internal and external anions can exchange. Variable-temperature 19F NMR spectroscopy was used to investigate the dynamic behaviour of the cages with X =[BF4]– and [PF6]– in MeCN solution: in both cases two separate signals, corresponding to external and internal anions, are clear at 233 K which have coalesced to a single signal at room temperature. Analysis of the linewidth of the minor signal (for the internal anion) at various temperatures below coalescence gave an activation energy for anion exchange of ca. 50 kJ mol–1 in each case, a figure which suggests that anion exchange can occur via a conformational rearrangement of the cage superstructure in solution rather than opening of the cavity by cleavage of metal–ligand bonds.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '10', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/B409809A', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2004', 'status_changed_hour' => '13', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '4158' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '4158', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bell', 'eprintid' => '4158', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Zoe R.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '4158', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Michael D.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '5', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '2', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Self-assembly of a molecular M8L12 cube having S6 symmetryElectronic supplementary information (ESI) available: Fig. S1 and S2. See http://www.rsc.org/suppdata/cc/b3/b307172n/', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/41/58', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '5', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b307172n', 'succeeds' => undef, 'datestamp_month' => '5', 'commentary' => undef, 'lastmod_day' => '5', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '2432-2433', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '2', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '13', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '2', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '4158', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '5', 'event_dates' => undef, 'fulltimestamp' => '20030000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '13', 'number' => '19', 'rev_number' => '9', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '5', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '5', 'datestamp_day' => '5', 'abstract' => 'Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16(X = perchlorate or tetrafluoroborate); [Zn8(L1)12](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '5', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b307172n', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2003', 'status_changed_hour' => '13', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '5476' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1371643860', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Gillie', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lisa .J.', 'creators_id' => 'l.j.gillie@hud.ac.uk' }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Bullock', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Sam', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Whitehead', 'eprintid' => '5476', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Martina', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '49', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Isomeric pyridyl-thiazole donor units for metal ion recognition in bi- and tri-metallic helicates', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/54/76', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '12', 'refereed' => 'TRUE', 'contact_email' => 'l.j.gillie@hud.ac.uk', 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b908911j', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '19', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '4856-4858', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '19', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '49', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 7, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '5476', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2013', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '6', 'event_dates' => undef, 'fulltimestamp' => '20090700', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '12', 'number' => '32', 'rev_number' => '9', 'edit_lock_user' => '3483', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'mcrc', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '26', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '26', 'datestamp_day' => '26', 'abstract' => 'Linking two isomeric tridentate N-chelates together produces a hetero-ditopic ligand capable of selectively binding Hg2+ and Zn2+ ions in a double-stranded helicate.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '26', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b908911j', 'volume' => '2009', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2009', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '568' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '6' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Ward', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '6', 'creators_name_given' => 'Michael D.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Adams', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Harry', 'creators_id' => undef }, '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Argent', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Stephen P.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Mamula', 'eprintid' => '568', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Olimpia', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '3', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '5', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Coordination Chemistry of Tetradentate N-Donor Ligands Containing Two Pyrazolyl-Pyridine Units Separated by a 1,8-Naphthyl Spacer: Dodecanuclear and Tetranuclear Coordination Cages and Cyclic Helicates', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/05/68', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '0', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://pubs.acs.org/cgi-bin/abstract.cgi/inocaj/2006/45/i10/abs/ic060157d.html', 'succeeds' => undef, 'datestamp_month' => '3', 'commentary' => undef, 'lastmod_day' => '30', 'publisher' => 'American Chemical Society', 'pagerange' => '3905-3919', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Inorganic Chemistry', 'lastmod_second' => '24', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '0020-1669', 'datestamp_hour' => '12', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '5', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 4, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '568', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2008', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '10', 'event_dates' => undef, 'fulltimestamp' => '20060400', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '17', 'number' => '10', 'rev_number' => '32', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '30', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '13', 'datestamp_day' => '13', 'abstract' => 'The tetradentate ligand Lnaph contains two N-donor bidentate pyrazolyl-pyridine units connected to a 1,8-naphthyl core via methylene spacers; L*45 and L*56 are chiral ligands with a structure similar to that of Lnaph but bearing pinene groups fused to either C4 and C5 or C5 and C6 of the terminal pyridyl rings. The complexes [Cu(Lnaph)](OTf) and [Ag(Lnaph)](BF4) have unremarkable mononuclear structures, with CuI being four-coordinate and AgI being two-coordinate with two additional weak interactions (i.e., "2 + 2" coordinate). In contrast, [Cu4(Lnaph)4][BF4]4 is a cyclic tetranuclear helicate with a tetrafluoroborate anion in the central cavity, formed by an anion-templating effect; electrospray mass spectrometry (ESMS) spectra show the presence of other cyclic oligomers in solution. The chiral ligands show comparable behavior, with [Cu(L*45)](BF4) and [Ag(L*45)](ClO4) having similar mononuclear crystal structures and with the ligands being tetradentate chelates. In contrast, [Ag4(L*56)4](BF4)4 is a cyclic tetranuclear helicate in which both diastereomers of the complex are present in the crystal; the two diastereomers have similar gross geometries but are significantly different in detail. Despite their different crystal structures, [Ag(L*45)](ClO4) and [Ag4(L*56)4](BF4)4 behave similarly in solution according to ESMS studies, with a range of cyclic oligomers (up to Ag9L9) forming. With transition-metal dications CoII, CuII, and CdII, Lnaph generates a series of unusual dodecanuclear coordination cages [M12(Lnaph)18]X24 (X- = ClO4- or BF4-) in which the 12 metal ions occupy the vertices of a truncated tetrahedron and a bridging ligand spans each of the 18 edges. The central cavity of each cage can accommodate four counterions, and each cage molecule is chiral, with all 12 metal trischelates being homochiral; the crystals are racemic. Extensive aromatic stacking between ligands around the periphery of the cages appears to be a significant factor in their assembly. The chiral analogue L*45 forms the simpler tetranuclear, tetrahedral coordination cage [Zn4(L*45)6](ClO4)8, with one anion in the central cavity; the steric bulk of the pinene chiral auxiliaries prevents the formation of a dodecanuclear cage, although trace amounts of [Zn12(L*45)18](ClO4)24 can be detected in solution by ESMS. Formation of [Zn4(L*45)6](ClO4)8 is diastereoselective, with the chirality of the pinene groups controlling the chirality of the tetranuclear cage. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '30', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => '10.1021/ic060157d', 'volume' => '45', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2006', 'status_changed_hour' => '12', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '8222' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => '1280415186', 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Amoroso', 'eprintid' => '8222', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Angelo J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Andrews', 'eprintid' => '8222', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Michael', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '8222', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '8222', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '7', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2010', 'fileinfo' => '', 'status_changed_second' => '0', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Responsive, di-metallic lanthanide complexes of a piperazine-bridged bis-macrocyclic ligand: modulation of visible luminescence and proton relaxivity', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/82/22', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '57', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/B923988J', 'succeeds' => undef, 'datestamp_month' => '7', 'commentary' => undef, 'lastmod_day' => '29', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '3407-3411', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2010', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '0', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '14', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '0', 'note' => undef, 'edit_lock_until' => '0', 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 3, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '8222', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '7', 'event_dates' => undef, 'fulltimestamp' => '20100300', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '14', 'number' => '14', 'rev_number' => '7', 'edit_lock_user' => '3494', 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '57', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '29', 'datestamp_day' => '29', 'abstract' => 'The synthesis of a functionalised bis-macrocyclic ligand (L1) is described together with the di-metallic LnIII complexes, Ln2-L1 (Ln = GdIII, EuIII). Luminescence and proton NMRD measurements show the complexes display differentiated responses to Cu(II) and Hg(II)', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '57', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/B923988J', 'volume' => '39', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '14', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1449' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '1449', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1449', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1449', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Thomas', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Baylies', 'eprintid' => '1449', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Christian J.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1449', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'John C.', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '48', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Allosteric and electrostatic reprogramming of a ditopic ligand', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/14/49', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '36', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1002/anie.200460424', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Wiley - VCH Verlag GmbH & Co. KGaA', 'pagerange' => '4515-4518', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Angewandte Chemie International Edition', 'lastmod_second' => '8', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14337851', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '48', 'note' => 'UoA 18 (Chemistry)', 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 8, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1449', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20040800', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '34', 'rev_number' => '14', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '59', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '11', 'datestamp_day' => '11', 'abstract' => 'Molecular work at Huddersfield and crystallography at the University of Bristol. This work is particularly novel as it describes, for the first time, the ability to change the specific information inherent within a ligand strand. Baylies PhD student, Harding research technician at Huddersfield. Others at Bristol.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '59', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1002/anie.200460424', 'volume' => '43', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2004', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '6356' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Fisher', 'eprintid' => '6356', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Julie', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Hardie', 'eprintid' => '6356', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Michaele J.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Carruthers', 'eprintid' => '6356', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Christopher', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '6356', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '11', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '57', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Host–guest influence on metallo-supramolecular assemblies with a cyclotriveratrylene-type ligand', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/63/56', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '8', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b914285a', 'succeeds' => undef, 'datestamp_month' => '11', 'commentary' => undef, 'lastmod_day' => '24', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '355-357', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Dalton Transactions', 'lastmod_second' => '9', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '14779226', 'datestamp_hour' => '16', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '57', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 1, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '6356', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2010', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '3', 'event_dates' => undef, 'fulltimestamp' => '20100100', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '9', 'number' => '2', 'rev_number' => '8', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '57', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '23', 'datestamp_day' => '23', 'abstract' => 'The structure-directing effect of guest binding in metallo-supramolecular assemblies of host-type ligands is observed with a 2-D coordination polymer formed between Cd(OAc)2 and tris(4-pyridylmethylamino)cyclotriguaiacylene in the presence of the globular guest o-carborane, and a trinuclear Cd(II) complex formed in solution in the absence of the bulky guest.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '57', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b914285a', 'volume' => '39', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2010', 'status_changed_hour' => '16', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '1448' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Zeng', 'eprintid' => '1448', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Zuotao', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jeffery', 'eprintid' => '1448', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'John C.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '1448', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '1448', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Riis-Johannessen', 'eprintid' => '1448', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Thomas', 'creators_id' => undef } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '8', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2008', 'fileinfo' => '', 'status_changed_second' => '51', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Anion control of ligand self-recognition in a triple helical array ', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/14/48', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '35', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b313218h', 'succeeds' => undef, 'datestamp_month' => '8', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '654-655', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2008', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '10', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1364-548X', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '51', 'note' => 'UoA 18 (Chemistry)', 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => undef, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '1448', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20040000', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '6', 'rev_number' => '13', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '1', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'QD', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '48', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '11', 'datestamp_day' => '11', 'abstract' => 'Self-assembly of the ligand L1 with Co2+ into a dinuclear triple helicate [Co2(L1)3]4+ produces an anion binding pocket which encapsulates perchlorate anions. Furthermore we demonstrate how this ability to bind anions can control ligand self-recognition properties. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '48', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b313218h', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2004', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3462' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Laye', 'eprintid' => '3462', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Rebecca H.', 'creators_id' => undef }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '3462', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Andrews', 'eprintid' => '3462', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Michael', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3462', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '55', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'Quinoxaline sensitised lanthanide ion luminescence: Syntheses, spectroscopy and X-ray crystal structure of Na{1,4,7-tris[(N-diethyl)carbamoylmethyl]-1,4,7,10-tetraazacyclododecane-10-(2-methylquinoxaline)}I3 C7H8', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/62', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '38', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => 11, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1016/j.poly.2008.04.010', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '26', 'publisher' => 'Elsevier', 'pagerange' => '2365-2371', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Polyhedron', 'lastmod_second' => '48', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '02775387', 'datestamp_hour' => '15', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '55', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 8, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3462', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20080811', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '11', 'rev_number' => '11', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'bmsrc', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '35', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '20', 'datestamp_day' => '20', 'abstract' => 'The synthesis of a quinoxaline-appended aza-macrocyclic ligand together with corresponding LnIII complexes are described. The luminescence properties of the complexes show that the quinoxaline unit sensitises both visible (EuIII) and near-IR (NdIII and YbIII) emitting lanthanide ions. UV–Vis absorption and time-resolved photophysical studies together with X-ray structural data suggest that as well as contributing chromophorically, the quinoxaline moiety generally participates in the first coordination sphere of LnIII. The luminescent pH response of the EuIII complex is also reported. The form of the steady state spectrum changes profoundly in the pH range 2–12, implying a change in the coordination environment, which was confirmed with time-resolved lifetime measurements that suggest an increase in europium inner sphere hydration at acidic pH. ', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '6', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '35', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1016/j.poly.2008.04.010', 'volume' => '27', 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '15', 'gscholar_cluster' => undef, 'producers_name_family' => undef }, '3487' => { 'funders' => undef, 'conductors_name_family' => undef, 'num_pieces' => undef, 'department' => undef, 'contributors_id' => undef, 'gscholar_datestamp_second' => undef, 'keywords' => undef, 'lyricists_name_lineage' => undef, 'lyricists_id' => undef, 'edit_lock_since' => undef, 'creatorlist' => { '4' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Pope', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '4', 'creators_name_given' => 'Simon J. A.', 'creators_id' => undef }, '1' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Harding', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '1', 'creators_name_given' => 'Lindsay P.', 'creators_id' => 'l.p.harding@hud.ac.uk' }, '3' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Kariuki', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '3', 'creators_name_given' => 'Benson M.', 'creators_id' => undef }, '0' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Felton', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '0', 'creators_name_given' => 'Cara E.', 'creators_id' => undef }, '2' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Jones', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '2', 'creators_name_given' => 'Jennifer E.', 'creators_id' => undef }, '5' => { 'creators_name_lineage' => '', 'creators_name_family' => 'Rice', 'eprintid' => '3487', 'creators_name_honourific' => '', 'pos' => '5', 'creators_name_given' => 'Craig R.', 'creators_id' => 'c.r.rice@hud.ac.uk' } }, 'exhibitors_id' => undef, 'latitude' => undef, 'replacedby' => undef, 'status_changed_month' => '2', 'editors_name_honourific' => undef, 'admin_note' => undef, 'event_title' => undef, 'date_type' => 'published', 'pres_type' => undef, 'longitude' => undef, 'creators_name_honourific' => '', 'include_in_hebci' => 'no', 'producers_name_honourific' => undef, 'scopus_citation_count' => undef, 'datestamp_year' => '2009', 'fileinfo' => '', 'status_changed_second' => '28', 'exhibitors_name_honourific' => undef, 'editors_id' => undef, 'title' => 'A wavelength and lifetime responsive cryptate-containing fluorescent probe for zinc ions in water', 'corp_creators' => undef, 'contributors_name_given' => undef, 'alt_title' => undef, 'contributors_name_family' => undef, 'sponsors' => undef, 'output_media' => undef, 'editors_name_lineage' => undef, 'dir' => 'disk0/00/00/34/87', 'overlay_journal_id' => undef, 'gscholar_datestamp_year' => undef, 'ispublished' => 'pub', 'item_issues_count' => '0', 'conductors_name_given' => undef, 'sword_depositor' => undef, 'full_text_status' => 'none', 'lastmod_minute' => '22', 'refereed' => 'TRUE', 'contact_email' => undef, 'copyright_holders' => undef, 'date_day' => undef, 'gscholar_impact' => undef, 'official_url' => 'http://dx.doi.org/10.1039/b813775g', 'succeeds' => undef, 'datestamp_month' => '2', 'commentary' => undef, 'lastmod_day' => '25', 'publisher' => 'Royal Society of Chemistry', 'pagerange' => '6185-6187', 'include_in_pedagogical' => 'no', 'task_purpose' => undef, 'status_changed_year' => '2009', 'book_title' => undef, 'thesis_name' => undef, 'event_location' => undef, 'type' => 'article', 'publication' => 'Chemical Communications', 'lastmod_second' => '28', 'place_of_pub' => undef, 'contributors_name_honourific' => undef, 'gscholar_datestamp_day' => undef, 'issn' => '1359-7345', 'datestamp_hour' => '10', 'exhibitors_name_given' => undef, 'creators_name_family' => 'Harding', 'composition_type' => undef, 'producers_id' => undef, 'datestamp_second' => '28', 'note' => undef, 'edit_lock_until' => undef, 'editor_note' => undef, 'pedagogic_type' => undef, 'date_month' => 12, 'rights' => undef, 'contributors_type' => undef, 'scopus_id' => undef, 'eprintid' => '3487', 'producers_name_given' => undef, 'thesis_type' => undef, 'projects' => undef, 'lastmod_year' => '2009', 'data_type' => undef, 'gscholar_datestamp_minute' => undef, 'editors_name_given' => undef, 'isbn' => undef, 'include_in_cv' => 'yes', 'editors_name_family' => undef, 'lastmod_month' => '2', 'event_dates' => undef, 'fulltimestamp' => '20081200', 'learning_level' => undef, 'conductors_name_lineage' => undef, 'pages' => undef, 'source' => undef, 'lastmod_hour' => '10', 'number' => '46', 'rev_number' => '10', 'edit_lock_user' => undef, 'series' => undef, 'creators_name_lineage' => '', 'pos' => '0', 'metadata_visibility' => 'show', 'eprint_status' => 'archive', 'creators_name_given' => 'Lindsay P.', 'exhibitors_name_lineage' => undef, 'divisions' => 'sas', 'institution' => undef, 'subjects' => 'Q1', 'gscholar_datestamp_hour' => undef, 'producers_name_lineage' => undef, 'lyricists_name_given' => undef, 'completion_time' => undef, 'status_changed_minute' => '22', 'conductors_name_honourific' => undef, 'exhibitors_name_family' => undef, 'lyricists_name_honourific' => undef, 'event_type' => undef, 'importid' => undef, 'status_changed_day' => '25', 'datestamp_day' => '25', 'abstract' => 'A diamino-functionalised cryptate can react irreversibly with butanal in water, in the presence of an excess of a metal ion, to form a cyclised bis-aminal complex, which displays metal-dependent luminescence properties.', 'creators_id' => 'l.p.harding@hud.ac.uk', 'contributors_name_lineage' => undef, 'userid' => '3494', 'patent_applicant' => undef, 'monograph_type' => undef, 'datestamp_minute' => '22', 'lyricists_name_family' => undef, 'sword_slug' => undef, 'id_number' => 'doi:10.1039/b813775g', 'volume' => undef, 'gscholar_datestamp_month' => undef, 'conductors_id' => undef, 'suggestions' => undef, 'referencetext' => undef, 'date_year' => '2008', 'status_changed_hour' => '10', 'gscholar_cluster' => undef, 'producers_name_family' => undef } };

2014

Harding, L., Parkes, G. and Townend, J. (2014) ‘Parameters affecting ion intensities in transmission-mode Direct Analysis in Real-Time mass spectrometryAnalyst , 139 (17), pp. 4176-4180. ISSN 0003-2654

2013

Clegg, O., Harding, L., Miller, J. and Rice, C. (2013) ‘Tricarbonylchlorido(6'7'-dihydro-5’H-spiro[cyclopentane-1,6'-dipyrido-[3,2-d:2',3'-f][1,3]diazepine]-?2N1,N11)-rhenium(I)Acta Crystallographica Section E , 69 (10), p. m526. ISSN 1600-5368

Clegg, O., Harding, L., Miller, J. and Rice, C. (2013) ‘Tricarbonylchlorido(6’,7’-dihydro-5’H-spiro[cyclohexane-1,6’-dipyrido[3,2-d :2’,3’-f][1,3]diazepine]-?2N1,N11)rhenium(I)Acta Crystallographica Section E , 69, p. m527. ISSN 1600-5368

Cooke, D., Cross, J., Fennessy, R., Harding, L., Rice, C. and Slater, C. (2013) ‘Steric control of the formation of dinuclear double helicate and dinuclear meso-helicate assembliesChemical Communications , 49 (71), pp. 7785-7787. ISSN 1359-7345

Bullock, S., Harding, L., Moore, M., Mills, A., Piela, S., Rice, C., Towns-Andrews, E. and Whitehead, M. (2013) ‘Synthesis of Ligands Containing N-oxide Donor Atoms and Their Assembly into Metallosupramolecular Structures.Dalton Transactions . ISSN 1477-9226

2012

Bullock, S., Hallett, A., Harding, L., Higginson, J., Piela, S., Pope, S. and Rice, C. (2012) ‘Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroidsDalton Transactions . ISSN 14779226

Ahmed, A., Harding, L. and Chrystyn, H. (2012) ‘Urinary pharmacokinetic methodology to determine the relative lung availability of inhaled beclometasoneBritish Journal of Clinical Pharmacology , 74 (3), pp. 456-464. ISSN 1365-2125

Henkelis, J., Barnett, S., Harding, L. and Hardie, M. (2012) ‘Coordination polymers utilizing N-oxide functionalised host ligandsInorganic Chemistry , 51 (20), pp. 10657-10674. ISSN 0020-1669

Cox, N., Harding, L., Jones, J., Pope, S., Rice, C. and Adams, H. (2012) ‘Probing solution behaviour of metallosupramolecular complexes using pyrene fluorescenceDalton Transactions , 41 (5), pp. 1568-1573. ISSN 14779226

Sutton, C., Harding, L., Hardie, M., Riis-Johannessen, T. and Rice, C. (2012) ‘Allosteric Effects in a Ditopic Ligand Containing Bipyridine and Tetra-aza-crown Donor UnitsChemistry - A European Journal , 18 (12), pp. 3464-3467. ISSN 0947-6539

2011

Henkelis, J., Ronson, T., Harding, L. and Hardie, M. (2011) ‘M3L2 metallo-cryptophanes: [2]catenane and simple cagesChemical Communications , 47 (23), pp. 6560-6562. ISSN 13597345

Clegg, O., Fennessy, R., Harding, L., Rice, C., Riis-Johannessen, T. and Fletcher, N. (2011) ‘Diastereoselective assembly of pentanuclear circular helicatesDalton Transactions , 40 (45), pp. 12381-12387. ISSN 1477-9226

2010

Little, M., Halcrow, M., Harding, L. and Hardie, M. (2010) ‘Ag(I) organometallic coordination polymers and capsule with tris-allyl cyclotriveratrylene derivativesInorganic Chemistry , 49 (20), pp. 9486-9496. ISSN 00201669

Allen, K., Faulkner, R., Harding, L., Rice, C., Riis-Johannessen, T., Voss, M. and Whitehead, M. (2010) ‘Head-To-Tail and Heteroleptic Pentanuclear Circular HelicatesAngewandte Chemie International Edition , 49 (37), pp. 6655-6658. ISSN 1433-7851

Bain, L., Bullock, S., Harding, L., Riis-Johannessen, T., Midgley, G., Rice, C. and Whitehead, M. (2010) ‘Controlling the formation of metallosupramolecular assemblies by metal ionic radiiChemical Communications , 46 (20), pp. 3496-3498. ISSN 1359-7345

Andrews, M., Jones, J., Harding, L. and Pope, S. (2010) ‘Luminescent probes based on water-soluble, dual-emissive lanthanide complexes: metal ion-induced modulation of near-IR emissionChemical Communications . ISSN 1359-7345

Andrews, M., Amoroso, A., Harding, L. and Pope, S. (2010) ‘Responsive, di-metallic lanthanide complexes of a piperazine-bridged bis-macrocyclic ligand: modulation of visible luminescence and proton relaxivityDalton Transactions , 39 (14), pp. 3407-3411. ISSN 14779226

Ronson, T., Carruthers, C., Fisher, J., Brotin, T., Harding, L., Rizkallah, P. and Hardie, M. (2010) ‘Tripodal 4-Pyridyl-Derived Host Ligands and Their Metallo-Supramolecular Chemistry: Stella Octangula and Bowl-Shaped AssembliesInorganic Chemistry , 49 (2), pp. 675-685. ISSN 00201669

Carruthers, C., Fisher, J., Harding, L. and Hardie, M. (2010) ‘Host–guest influence on metallo-supramolecular assemblies with a cyclotriveratrylene-type ligandDalton Transactions , 39 (2), pp. 355-357. ISSN 14779226

2009

Bullock, S., Felton, C., Fennessy, R., Harding, L., Andrews, M., Pope, S., Rice, C. and Riis-Johannessen, T. (2009) ‘Coumarin-based luminescent ligand that forms helicates with dicationic metal ionsDalton Transactions , 47, pp. 10570-10573. ISSN 14779226

Lu, J., Turner, D., Harding, L. and Batten, S. (2009) ‘Heteroligand Molecular “Stirrups” Using Conformationally Flexible Ditopic Pyridyl?Pyrazolyl LigandsInorganic Chemistry , 48 (16), pp. 7525-7527. ISSN 00201669

Lu, J., Turner, D., Harding, L., Byrne, L., Baker, M. and Batten, S. (2009) ‘Octapi Interactions: Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold ? InteractionsJournal of the American Chemical Society , 131 (30), pp. 10372-10373. ISSN 1520-5126

Bullock, S., Gillie, L., Harding, L., Rice, C., Riis-Johannessen, T. and Whitehead, M. (2009) ‘Isomeric pyridyl-thiazole donor units for metal ion recognition in bi- and tri-metallic helicatesChemical Communications , 2009 (32), pp. 4856-4858. ISSN 1359-7345

Ronson, T., Fisher, J., Harding, L., Rizkallah, P., Warren, J. and Hardie, M. (2009) ‘Stellated polyhedral assembly of a topologically complicated Pd4L4 ‘Solomon cube’Nature Chemistry , 1 (3), pp. 212-216. ISSN 17554330

2008

Felton, C., Harding, L., Jones, J., Kariuki, B., Pope, S. and Rice, C. (2008) ‘A wavelength and lifetime responsive cryptate-containing fluorescent probe for zinc ions in waterChemical Communications (46), pp. 6185-6187. ISSN 1359-7345

Carruthers, C., Ronson, T., Sumby, C., Westcott, A., Harding, L., Prior, T., Rizkallah, P. and Hardie, M. (2008) ‘The Dimeric “Hand-Shake” Motif in Complexes and Metallo-Supramolecular Assemblies of Cyclotriveratrylene-Based LigandsChemistry - A European Journal , 14 (33), pp. 10286-10296. ISSN 09476539

Tidmarsh, I., Faust, T., Adams, H., Harding, L., Russo, L., Clegg, W. and Ward, M. (2008) ‘Octanuclear Cubic Coordination CagesJournal of the American Chemical Society , 130 (45), pp. 15167-15175. ISSN 1520-5126

Andrews, M., Laye, R., Harding, L. and Pope, S. (2008) ‘Quinoxaline sensitised lanthanide ion luminescence: Syntheses, spectroscopy and X-ray crystal structure of Na{1,4,7-tris[(N-diethyl)carbamoylmethyl]-1,4,7,10-tetraazacyclododecane-10-(2-methylquinoxaline)}I3 C7H8Polyhedron , 27 (11), pp. 2365-2371. ISSN 02775387

Al-Rasbi, N., Tidmarsh, I., Argent, S., Adams, H., Harding, L. and Ward, M. (2008) ‘Mixed-Ligand Molecular Paneling: Dodecanuclear Cuboctahedral Coordination Cages Based on a Combination of Edge-Bridging and Face-Capping LigandsJournal of the American Chemical Society , 130 (35), pp. 11641-11649. ISSN 1520-5126

Westcott, A., Fisher, J., Harding, L., Rizkallah, P. and Hardie, M. (2008) ‘Self-Assembly of a 3-D Triply Interlocked Chiral [2]CatenaneJournal of the American Chemical Society , 130 (10), pp. 2950-2951. ISSN 1520-5126

Westcott, A., Fisher, J., Harding, L. and Hardie, M. (2008) ‘Flattened trigonal bipyramidal coordination assembly with trans geometryCrystEngComm , 10 (3), pp. 276-278. ISSN 1466-8033

Clayton, H., Harding, L., Irvine, J., Jeffery, J., Riis-Johannessen, T., Laws, A., Rice, C. and Whitehead, M. (2008) ‘Metal-specific allosteric activation and deactivation of a diamineChemical Communications (1), p. 108. ISSN 1364-548X

Mullice, L., Laye, R., Harding, L. and Buurma, N. (2008) ‘Rhenium complexes of chromophore-appended dipicolylamine ligands: syntheses, spectroscopic properties, DNA binding and X-ray crystal structureNew Journal of Chemistry , 32 (12), pp. 2140-2149. ISSN 1144-0546

2007

Ronson, T., Fisher, J., Harding, L. and Hardie, M. (2007) ‘Star-Burst Prisms with Cyclotriveratrylene-Type Ligands: A [Pd6L8]12+ Stella Octangular StructureAngewandte Chemie International Edition , 46 (47), pp. 9086-9088. ISSN 14337851

Riis-Johannessen, T., Harding, L., Jeffery, J., Moon, R. and Rice, C. (2007) ‘Allosteric deprogramming of a trinuclear heterometallic helicateDalton Transactions (16), pp. 1577-1587. ISSN 14779226

Ronson, T., Adams, H., Harding, L., Pope, S., Sykes, D., Faulkner, S. and Ward, M. (2007) ‘Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N?,O-donor units: structures and luminescence propertiesDalton Transactions (10), pp. 1006-1022. ISSN 14779226

Al-Rasbi, N., Adams, H., Harding, L. and Ward, M. (2007) ‘Coordination Behaviour of Bis-Terdentate N-Donor Ligands: Double- and single-stranded helicates, mesocates, and cyclic oligomers European Journal of Inorganic Chemistry , 2007 (30), pp. 4770-4780. ISSN 1434-1948

Ronson, T., Adams, H., Harding, L., Harrington, R., Clegg, W. and Ward, M. (2007) ‘Synthesis and structures of cadmium(II) complexes of a series of multinucleating N/S donor ligandsPolyhedron , 26 (12), pp. 2777-2785. ISSN 02775387

Jeffery, J., Rice, C., Harding, L., Baylies, C. and Riis-Johannessen, T. (2007) ‘Ligand Reprogramming in Dinuclear Helicate Complexes: A Consequence of Allosteric or Electrostatic Effects?Chemistry - A European Journal , 13 (18), pp. 5256-5271. ISSN 09476539

Baylies, C., Harding, L., Jeffery, J., Moon, R., Rice, C. and Riis-Johannessen, T. (2007) ‘Electrostatic control of the formation of heteroleptic transition metal helicatesNew Journal of Chemistry , 31 (8), pp. 1525-1529. ISSN 11440546

2006

Argent, S., Adams, H., Riis-Johannessen, T., Jeffery, J., Harding, L., Mamula, O. and Ward, M. (2006) ‘Coordination Chemistry of Tetradentate N-Donor Ligands Containing Two Pyrazolyl-Pyridine Units Separated by a 1,8-Naphthyl Spacer: Dodecanuclear and Tetranuclear Coordination Cages and Cyclic HelicatesInorganic Chemistry , 45 (10), pp. 3905-3919. ISSN 0020-1669

Coldwell, J., Felton, C., Harding, L., Moon, R., Pope, S. and Rice, C. (2006) ‘Barium induced modulation of NIR emission in a neodymium cryptate complexChemical Communications , 2006, pp. 5048-5050. ISSN 1364-548X

Argent, S., Adams, H., Harding, L. and Ward, M. (2006) ‘A closed molecular cube and an open book: two different products from assembly of the same metal salt and bridging ligand Dalton Transactions , 2006 (4), pp. 542-544. ISSN 1477-9226

Argent, S., Adams, H., Riis-Johannessen, T., Jeffery, J., Harding, L., Clegg, W., Harrington, R. and Ward, M. (2006) ‘Complexes of Ag(I), Hg(I) and Hg(II) with multidentate pyrazolyl-pyridine ligands: from mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenateDalton Transactions , 2006 (42), pp. 4996-5013. ISSN 1477-9226

Bokolinis, G., Riis-Johannessen, T., Harding, L., Jeffery, J., McLay, N. and Rice, C. (2006) ‘This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications Chemical Communications , pp. 1980-1982. ISSN 1364-548X

2005

Argent, S., Adams, H., Riis-Johannessen, T., Jeffery, J., Harding, L. and Ward, M. (2005) ‘High-nuclearity homoleptic and heteroleptic coordination cages based on tetra-capped truncated tetrahedral and cuboctahedral metal frameworks Journal of the American Chemical Society , 128 (1), pp. 72-73. ISSN 1520-5126

Riis-Johannessen, T., Jeffery, J., Robson, A., Rice, C. and Harding, L. (2005) ‘Solution and solid-state complexes of the potentially tetradentate pyridyl-thiazole ligand 6,6?-bis(4-methylthiazol-2-yl)-2,2?-bipyridine with Co, Ni, Cu, Cd, Hg, Cu and AgInorganica Chimica Acta , 358 (9), pp. 2781-2798. ISSN 0020-1693

Argent, S., Adams, H., Harding, L., Riis-Johannessen, T., Jeffery, J. and Ward, M. (2005) ‘Homo- and heteropolynuclear helicates with a ‘2 + 3 + 2’-dentate compartmental ligandNew Journal of Chemistry , 29 (7), pp. 904-911. ISSN 1144-0546

Argent, S., Riis-Johannessen, T., Jeffery, J., Harding, L. and Ward, M. (2005) ‘Diastereoselective formation and optical activity of an M4L6 cage complexChemical Communications (37), pp. 4647-4649. ISSN 1359-7345

Harding, L., Marshall, V., Hernandez, Y., Gu, Y., Maqsood, M., McLay, N. and Laws, A. (2005) ‘Structural characterisation of the highly branched exopolysaccharide produced by Lactobacillus delbrueckii subsp. Bulgaricus NCFB2074Carbohydrate Research , 340 (6), pp. 1107-1111. ISSN 0008-6215

Tsang, W., Ahmed, N., Hinchliffe, P., Wood, J., Harding, L., Laws, A. and Page, M. (2005) ‘Different transition-state structures for the reactions of ?-lactams and analogous ?-sultams with serine ?-lactamases Journal of the American Chemical Society , 127 (49), pp. 17556-17564. ISSN 1520-5126

Tsang, W., Ahmed, N., Harding, L., Hemming, K., Laws, A. and Page, M. (2005) ‘Acylation versus sulfonylation in the inhibition of elastase by 3-oxo-beta-sultams Journal of the American Chemical Society , 127 (25), pp. 8946-8947. ISSN 1520-5126

Baylies, C., Riis-Johannessen, T., Harding, L., Jeffery, J., Moon, R., Rice, C. and Whitehead, M. (2005) ‘Allosteric-Controlled Metal Specificity of a Ditopic LigandAngewandte Chemie International Edition , 44 (42), pp. 6909-6912. ISSN 1433-7851

2004

Baylies, C., Harding, L., Jeffery, J., Riis-Johannessen, T. and Rice, C. (2004) ‘Allosteric and electrostatic reprogramming of a ditopic ligandAngewandte Chemie International Edition , 43 (34), pp. 4515-4518. ISSN 14337851

Harding, L., Jeffery, J., Riis-Johannessen, T., Rice, C. and Zeng, Z. (2004) ‘Anion control of the formation of geometric isomers in a triple helical array Dalton Transactions (16), pp. 2396-2397. ISSN 14779226

Paul, R., Argent, S., Jeffery, J., Harding, L., Lynam, J. and Ward, M. (2004) ‘Structures and anion-binding properties of M4L6 tetrahedral cage complexes with large central cavitiesDalton Transactions (21), pp. 3453-3458. ISSN 14779226

Harding, L., Jeffery, J., Riis-Johannessen, T., Rice, C. and Zeng, Z. (2004) ‘Anion control of ligand self-recognition in a triple helical array Chemical Communications (6), pp. 654-655. ISSN 1364-548X

2003

Page, M., Hinchliffe, P., Wood, J., Harding, L. and Laws, A. (2003) ‘Novel mechanism of inhibiting b-lactamases by sulfonylation using b-sultams Bioorganic & Medicinal Chemistry Letters , 13 (24), pp. 4489-4492. ISSN 0960-894X

Paul, R., Bell, Z., Jeffery, J., Harding, L., McCleverty, J. and Ward, M. (2003) ‘Complexes of a bis-bidentate ligand with d10 ions: a mononuclear complex with Ag(I), and a tetrahedral cage complex with Zn(II) which encapsulates a fluoroborate anionPolyhedron , 22 (5), pp. 781-787. ISSN 02775387

Rice, C., Baylies, C., Harding, L., Jeffery, J., Paul, R. and Ward`, M. (2003) ‘Cadmium-containing pyridyl–thiazole complexes: crystal structures and solution behaviour of mononuclear, dinuclear double helicate and dinuclear triple helicate complexesPolyhedron , 22 (5), pp. 755-762. ISSN 02775387

Harding, L., Marshall, V., Elvin, M., Gu, Y. and Laws, A. (2003) ‘Structural characterisation of a perdeuteriomethylated exoploysaccharide by NMR spectroscopy: characterisation of the novel exopolysaccharide produced by Lactobacillus delbrueckii subsp. Bulgaricus EU23Carbohydrate Research , 338 (1), pp. 61-67. ISSN 0008-6215

Bell, Z., Harding, L. and Ward, M. (2003) ‘Self-assembly of a molecular M8L12 cube having S6 symmetryElectronic supplementary information (ESI) available: Fig. S1 and S2. See http://www.rsc.org/suppdata/cc/b3/b307172n/Chemical Communications (19), pp. 2432-2433. ISSN 1359-7345

2001

Rice, C., Baylies, C., Harding, L., Jeffery, J. and Paul, R. (2001) ‘Pyridyl-thiazole multidentate ligands: metal-specific recognition of a combination of ligands from a mixtureJournal of the Chemical Society Dalton Transactions (20), pp. 3039-3044. ISSN 1472-7773

Research Degree Supervision

I currently have two PhD students and a placement student working in my group.

Current group members

  • Rizwana Sadiq, PhD student: Synthesis of coordination complexes incorporating biologically-relevant molecules
  • Joshua Higginson, PhD student (with Prof. Craig Rice): Preparation of functional metallosupramolecular complexes
  • Roger Thornton, placement student

Former group members

  • Dr Amira Ahmed, (co-supervised with Prof. Henry Chrystyn)
    Br. J. Clin. Pharmacol., (2012), 74, 456–464
  • Dr Nicola Cox
    Dalton Trans., (2012), 41, 1568-1573
  • Robert Faulkner, placement student (2009-10)
    Angew. Chem. Int. Ed., (2010), 49, 6655-6658
  • Oliver Clegg, placement student (2010-11)
    Dalton Trans., (2011), 40, 12381-12387
  • Bill Rogerson, placement student (2011-12)
  • James Townend, placement student (2011-12)
  • • John Miller, placement student (2012-13), Acta Cryst. (2013), E69, m526, Acta Cryst. (2013), E69, m527
Last updated Thursday 6 March 2014
Thank you for your feedback.

Your feedback has been sent to the University Web/E-Marketing Team.

Excellent
Good
Satisfactory
Needs improvement

Excellent
Good
Satisfactory
Needs improvement

Excellent
Good
Satisfactory
Needs improvement

VAT registration number 516 3101 90

All rights reserved ©